Aqueous Supramolecular Polymers Based on Aromatic Amphiphiles: Rational Design, Complexity, and Functional Materials

被引：5

作者：

Rybtchinski, Boris ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

来源：

HIERARCHICAL MACROMOLECULAR STRUCTURES: 60 YEARS AFTER THE STAUDINGER NOBEL PRIZE II | 2013年 / 262卷

基金：

以色列科学基金会;

关键词：

Hydrophobic interactions; Membranes; Noncovalent materials; Perylene diimides; Self-assembly; -; water; HYDROPHOBIC INTERACTIONS; JANUS DENDRIMERS; WATER; NANOSTRUCTURES; ASSEMBLIES; MOLECULES; CHEMISTRY; MEMBRANES; DYES; AGGREGATION;

D O I：

10.1007/12_2013_250

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Self-assembled polymeric nanoscale systems that are robust yet adaptive are of primary importance for fabricating multifunctional stimuli-responsive nanomaterials. Noncovalent interactions in water can be strong, and biological systems exhibit excellent robustness and adaptivity. Synthetic amphiphiles can also result in robust assemblies in water. Can we rationally design water-based noncovalent polymers? Can we program them to perform useful functions that rival covalent materials? We review here advancements related to these questions, focusing on aromatic self-assembly in aqueous media. Regarding functional materials, we present examples from our work on water-based recyclable noncovalent membranes, which can be used for size-selective separations of nanoparticles and biomolecules. These systems introduce the paradigm of noncovalent nanomaterials as a versatile and environmentally friendly alternative to covalent materials. We also address emerging rational design principles for creating 1D, 2D, and 3D functional nanoarrays hierarchically assembled from well-defined molecular units in aqueous media, enabling new synthetic strategies for fabricating complex water-based materials.

引用

页码：363 / 387

页数：25

共 67 条

[11] Polycaps: Reversibly formed polymeric capsules [J].

Castellano, RK ;

Rudkevich, DM ;

Rebek, J .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1997, 94 (14) :7132-7137

[12] Interfaces and the driving force of hydrophobic assembly [J].

Chandler, D .

NATURE, 2005, 437 (7059) :640-647

[13] Self-assembled π-stacks of functional dyes in solution: structural and thermodynamic features [J].

Chen, Zhijian ;

Lohr, Andreas ;

Saha-Moeller, Chantu R. ;

Wuerthner, Frank .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (02) :564-584

[14] Self-Assembly of Peptide Amphiphiles: From Molecules to Nanostructures to Biomaterials [J].

Cui, Honggang ;

Webber, Matthew J. ;

Stupp, Samuel I. .

BIOPOLYMERS, 2010, 94 (01) :1-18

[15] Supramolecular Polymerization [J].

De Greef, Tom F. A. ;

Smulders, Maarten M. J. ;

Wolffs, Martin ;

Schenning, Albert P. H. J. ;

Sijbesma, Rint P. ;

Meijer, E. W. .

CHEMICAL REVIEWS, 2009, 109 (11) :5687-5754

[16] One-dimensional optoelectronic nanostructures derived from the aqueous self-assembly of π-conjugated oligopeptides [J].

Diegelmann, Stephen R. ;

Gorham, Justin M. ;

Tovar, John D. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13840-13841

[17] Water gelation by small organic molecules [J].

Estroff, LA ;

Hamilton, AD .

CHEMICAL REVIEWS, 2004, 104 (03) :1201-1217

[18] Ionic self-assembly: Facile synthesis of supramolecular materials [J].

Faul, CFJ ;

Antonietti, M .

ADVANCED MATERIALS, 2003, 15 (09) :673-683

[19] Molecular Assemblies of Perylene Bisimide Dyes in Water [J].

Goerl, Daniel ;

Zhang, Xin ;

Wuerthner, Frank .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (26) :6328-6348

[20] Economical Design in Noncovalent Nanoscale Synthesis: Diverse Photofunctional Nanostructures Based on a Single Covalent Building Block [J].

Golubkov, Galina ;

Weissman, Haim ;

Shirman, Elijah ;

Wolf, Sharon G. ;

Pinkas, Iddo ;

Rybtchinski, Boris .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (05) :926-930

← 1 2 3 4 5 6 7 →