Effect of rare earth dopants on structural and mechanical properties of nanoceria synthesized by combustion method

被引:12
作者
Akbari-Fakhrabadi, A. [1 ]
Meruane, V. [1 ]
Jamshidijam, M. [2 ,3 ]
Gracia-Pinilla, M. A. [4 ,5 ]
Mangalaraja, R. V. [2 ]
机构
[1] Univ Chile, Dept Mech Engn, Adv Mat Lab, Santiago, Chile
[2] Univ Concepcion, Dept Mat Engn, Adv Ceram & Nanotechnol Lab, Concepcion, Chile
[3] Islamic Azad Univ, Sirjan Branch, Dept Mat Engn, Sirjan, Iran
[4] Univ Autonoma Nuevo Leon, Fac Ciencias Fismatemat, San Nicolas De Los Garza, NL, Mexico
[5] Univ Autonoma Nuevo Leon, Ctr Invest & Innovac Desarrollo Ingn & Tecnol, Apodaca, NL, Mexico
来源
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 2016年 / 649卷
关键词
Combustion synthesis; Doped ceria; Mesoporous; Mechanical properties; DOPED CERIA; ELASTIC PROPERTIES; FRACTURE-TOUGHNESS; ELECTROLYTES; INDENTATION; MODULUS; OXIDES;
D O I
10.1016/j.msea.2015.09.125
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Structural characteristics of combustion synthesized, calcined and densified pure and doped nanoceria with tri-valent cations of Er, Y, Gd, Sm and Nd were analyzed by X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). The results showed that the as-synthesized and calcined nanopowders were mesoporous and calculated lattice parameters were close to theoretical ion-packing model. The effect of dopants on elastic modulus, microhardness and fracture toughness of sintered pure and doped ceria were investigated. It was observed that tri-valent cation dopants increased the hardness of the ceria, whereas the fracture toughness and elastic modulus were decreased. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:168 / 173
页数:6
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