Syntheses, Structures and Luminescent Properties of Two Zinc(II) Coordination Polymers Constructed by Acetate and Pyridyl-Containing Ligands

被引：1
作者：
Jiang Zheng-Jing [1 ]
Yin Jing-Zhou [1 ]
Li Rong-Qing [1 ]
Zhang Zai-Chao [1 ]
Lu Lu-De [2 ]
机构：
[1] Huaiyin Normal Univ, Jiangsu Key Lab Chem Low Dimens Mat, Huaian 223300, Jiangsu, Peoples R China
[2] Nanjing Univ Sci & Technol, Minist Educ, Key Lab Soft Chem & Funct Mat, Nanjing 210094, Jiangsu, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2018年 / 34卷 / 04期
关键词：
zinc; coordination polymer; crystal structure; luminescent property; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; ZN(II); ENCAPSULATION; COMPLEXES; SORPTION;
D O I：
10.11862/CJIC.2018.086
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two coordination polymers, [Zn(CH3COO)(2)(INH)](n) (INH=isonicotinic acid hydrazid; isoniazid) (1) and [Zn(CH3COO)(2)(2-APy)](n) (2-APy=2-aminopyridine) (2) have been synthesized in DMF solution and structurally characterized by elemental analysis, IR spectra, single-crystal and powder X-ray diffractions. Structural analyses reveal that polymer 1 exhibits a 2-dimensional (2D) infinite layer framework, and the resulting 2D structure is interconnected by hydrogen-bond interactions to lead to a 3D supramolecular architecture. It crystallizes in the monoclinic system, space group P2(1)/c, with cell parameters a=0.914 44(17) nm, b=0.161 86(3) nm, c=0.871 75(16) nm, beta=96.181(3)degrees, V=1.282 8(4) nm(3), Z=4. Polymer 2 is an infinite 1D zig-zag chain. Polymer 2 crystallizes in the triclinic system, space group P (1) over bar, with cell parameters a=0.747 0(4) nm, b=0.814 5(5) nm, c=1.895 7(11) nm, alpha=88.276(8)degrees, beta=86.202(8)degrees, gamma=84.334(8)degrees, V=1.144 9(11) nm(3), Z=2. The solid-state luminescent properties of two polymers have also been investigated at room temperature. CCDC: 870030, 1; CCDC: 1524913, 2.
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页码：719 / 727
页数：9
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