Novel two-dimensional metal-organic framework with unprecedented trimeric building unit constructed from bridging water molecules

被引：12
作者：
Livage, C
Guillou, N
Chaigneau, J
Rabu, P
机构：
[1] Univ Versailles, Lab Lavoisier Versailles, CNRS, UMR 8180, F-78035 Versailles, France
[2] Inst Phys & Chim Mat Strasbourg, CNRS, UMR 7504, F-67037 Strasbourg, France
来源：
MATERIALS RESEARCH BULLETIN | 2006年 / 41卷 / 05期
关键词：
magnetic properties; X-ray diffraction;
D O I：
10.1016/j.materresbull.2006.02.009
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A novel two-dimensional nickel trimesate (1,3,5-benzenctficarboxylate), Ni-3(C9O6H3)(2)(H2O)(8), has been obtained by solvothermal route. Its structure is built up from linear trimers of nickel, {Ni3O8(mu(2)-OH2)(2)(H2O)(6)}, connected by trimesate anions. It crystallizes in the triclinic system, space group P-1, with a = 6.6960(3), b = 9.6446(3), c = 10.1114(3) angstrom, alpha = 112.638(1)degrees, beta = 94.008(1)degrees, gamma = 106.476(1)degrees, V = 565.99(4) angstrom(3). Synthesis, X-ray structure determination, thermogravimetric analysis and magnetic properties are presented. (C) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：981 / 986
页数：6
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