P-ρ-T data of liquids:: Summarization and evaluation.: 8.: Miscellaneous compounds

被引:44
作者
Cibulka, I [1 ]
Takagi, T
机构
[1] Inst Chem Technol, Dept Phys Chem, CR-16628 Prague, Czech Republic
[2] Kyoto Inst Technol, Kyoto 6068585, Japan
关键词
D O I
10.1021/je0200463
中图分类号
O414.1 [热力学];
学科分类号
摘要
The published experimental data for 53 compounds (eight amines, eight nitriles, four N-heterocyclic compounds, six nitro compounds, four amides, four other compounds containing C, H, O, and N atoms, six halogenated alcohols, five fluoroethers, and eight miscellaneous compounds) are summarized and reviewed, and the parameters of the Tait equation are given for 49 substances. This equation allows the calculation of smoothed values of either the volume ratio, V(P)/V(P-ref), and related properties (relative density, rho(P)/rho(P-ref), compression, {1 - rho(P-ref)/rho(P)}) or, using density data at atmospheric pressure (P-ref = 0.1 MPa) or at saturation (P-ref = P-sat), the liquid densities of the substances over a temperature and pressure range. Experimental values of isothermal compressibility at atmospheric pressure compiled from the literature are also summarized and compared with values calculated from the Tait equation.
引用
收藏
页码:1037 / 1070
页数:34
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