Transition metal phthalocyanine-modified shungite-based cathode catalysts for alkaline membrane fuel cell

被引：44

作者：

Mooste, Marek ^{[1
]}

Tkesheliadze, Tinatin ^{[1
]}

Kozlova, Jekaterina ^{[2
]}

Kikas, Arvo ^{[2
]}

Kisand, Vambola ^{[2
]}

Treshchalov, Alexey ^{[2
]}

Tamm, Aile ^{[2
]}

Aruvali, Jaan ^{[3
]}

Zagal, Jose H. ^{[4
]}

Kannan, Arunachala M. ^{[5
]}

Tammeveski, Kaido ^{[1
]}

机构：

[1] Univ Tartu, Inst Chem, Ravila 14a, EE-50411 Tartu, Estonia

[2] Univ Tartu, Inst Phys, W Ostwald Str 1, EE-50411 Tartu, Estonia

[3] Univ Tartu, Inst Ecol & Earth Sci, Vanemuise 46, EE-51014 Tartu, Estonia

[4] Univ Santiago Chile, Dept Quim Mat, Lab Electrocatalisis, Casilla 40,Correo 33, Santiago 9170022, Chile

[5] Arizona State Univ, Polytech Sch, Ira A Fulton Sch Engn, Mesa, AZ 85212 USA

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2021年 / 46卷 / 05期

关键词：

Electrocatalysis; Metal phthalocyanine; Shungite; Oxygen reduction reaction; Oxygen evolution reaction; Anion exchange membrane fuel cell; OXYGEN REDUCTION REACTION; CARBIDE-DERIVED CARBON; WATER-TREATMENT; NANOTUBE; ELECTROCATALYSTS; IRON; COMPOSITE; POLYMER; ELECTROREDUCTION; PERFORMANCE;

D O I：

10.1016/j.ijhydene.2020.10.231

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The alkaline anion exchange membrane fuel cell (AEMFC) is one of the green solutions for the growing need for energy conversion technologies. For the first time, we propose a natural shungite based non-precious metal catalyst (NPMC) as an alternative cathode catalyst to Pt-based materials for AEMFCs application. The Co and Fe phthalocyanine (Pc)modified shungite materials were prepared via pyrolysis and used for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) studies. The most promising ORR performance was observed in alkaline media for FePc-modified and acid-leached shungite-based NPMC material. The catalysts were also evaluated as cathode materials in a single cell AEMFC and peak power densities of 232 and 234 mW cm(-2) at 60 degrees C using H-2 and O-2 gases at 100% RH were observed for CoPc- and FePc-modified acid-treated materials, respectively. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：4365 / 4377

页数：13

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