Supramolecular Chirality in Porphyrin Chemistry

被引：61
作者：
Borovkov, Victor [1 ]
机构：
[1] Osaka Univ, Dept Appl Chem, Suita, Osaka 5650871, Japan
来源：
SYMMETRY-BASEL | 2014年 / 6卷 / 02期
关键词：
supramolecular chirality; supramolecular chemistry; chirality; porphyrin; host-guest; self-assembly; conformation; COUPLED CIRCULAR-DICHROISM; POSITIVE HOMOTROPIC ALLOSTERISM; ABSOLUTE CONFIGURATIONAL ASSIGNMENTS; BIS(PORPHYRINATE) DOUBLE-DECKER; ENHANCED OPTICAL-ACTIVITY; WALLED CARBON NANOTUBES; ZINC PORPHYRINS; MOLECULAR RECOGNITION; BIS(ZINC PORPHYRIN); DIPORPHYRIN NANOTWEEZERS;
D O I：
10.3390/sym6020256
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Supramolecular chirality, being an intelligent combination of supramolecular chemistry and chiral science, plays a decisive role in the functioning of various natural assemblies and has attracted much attention from the scientific community, due to different applications in modern technologies, medicine, pharmacology, catalysis and biomimetic research. Porphyrin molecules are of particular interest to study this phenomenon owing to their unique spectral, physico-chemical and synthetic properties. This review highlights the most important types of chiral porphyrin structures by using the best-suited representative examples, which are frequently used in the area of supramolecular chirality.
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收藏
页码：256 / 294
页数：39
相关论文
共 107 条
[1]   Induced circular dichroism by chiral molecular interaction [J].
Allenmark, S .
CHIRALITY, 2003, 15 (05) :409-422
[2]   Spectroscopic characterization of an assembled pair of free-base and zinc porphyrins linked by the cyclic β-sheet peptide Gramicidin S [J].
Arai, T ;
Araki, K ;
Maruo, N ;
Sumida, Y ;
Korosue, C ;
Fukuma, K ;
Kato, T ;
Nishino, N .
NEW JOURNAL OF CHEMISTRY, 2004, 28 (09) :1151-1159
[3]   Construction of monomeric and polymeric porphyrin compartments by a Pd(II)-pyridine interaction and their chiral twisting by a BINAP ligand [J].
Ayabe, M ;
Yamashita, K ;
Sada, K ;
Shinkai, S ;
Ikeda, A ;
Sakamoto, S ;
Yamaguchi, K .
JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (03) :1059-1066
[4]   Chlorins programmed for self-assembly [J].
Balaban, TS ;
Tamiaki, H ;
Holzwarth, AR .
SUPERMOLECULAR DYE CHEMISTRY, 2005, 258 :1-38
[5]   Tailoring porphyrins and chlorins for self-assembly in biomimetic artificial antenna systems [J].
Balaban, TS .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (08) :612-623
[6]   A Functionalized Spiro[chlorin-porphyrin]-Type 'Dimer' Dizinc Complex from Rapid [4+2] Self-cycloaddition of a Conjugated [ββ′-Bis(methylene)porphyrinato]zinc [J].
Banala, Srinivas ;
Sintic, Paul ;
Kraeutler, Bernhard .
HELVETICA CHIMICA ACTA, 2012, 95 (02) :211-220
[7]   Application of electronic circular dichroism in configurational and conformational analysis of organic compounds [J].
Berova, Nina ;
Di Bari, Lorenzo ;
Pescitelli, Gennaro .
CHEMICAL SOCIETY REVIEWS, 2007, 36 (06) :914-931
[8]   Supramolecular chirogenesis in bis-porphyrins: Interaction with chiral acids and application for the absolute configuration assignment [J].
Bhyrappa, Puttaiah ;
Borovkov, Victor V. ;
Inoue, Yoshihisa .
ORGANIC LETTERS, 2007, 9 (03) :433-435
[9]  
Borovkov VV, 2006, USP KHIM+, V75, P820
[10]   Effective Supramolecular Chirogenesis in Ethane-Bridged Bis-Porphyrinoids [J].
Borovkov, Victor .
SYMMETRY-BASEL, 2010, 2 (01) :184-200
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