Electron-spin excitation by implanting hydrogen into metallofullerene: the synthesis and spectroscopic characterization of Sc4C2H@Ih-C80

被引：20

作者：

Feng, Yongqiang ^{[1
]}

Wang, Taishan ^{[1
]}

Wu, Jingyi ^{[2
]}

Zhang, Zhuxia ^{[1
]}

Jiang, Li ^{[1
]}

Han, Hongbin ^{[3
]}

Wang, Chunru ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Lab Mol Nanostruct & Nanotechnol, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Anal Tech, Beijing 100049, Peoples R China

[3] Peking Univ, Hosp 3, Dept Radiol, Beijing 100191, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 81期

关键词：

CLUSTER; FULLERENE; SC3N-AT-C-80; ANIONS; EPR;

D O I：

10.1039/c4cc05783j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A hydrogen-containing endohedral metallofullerene, Sc4C2H@ I-h-C-80, was synthesized and its paramagnetism was measured by the low-temperature EPR spectrometry with a broad EPR signal. The electron-spin excitation by implanting the H-atom would be a new method for preparation of stable paramagnetic metallofullerenes.

引用

页码：12166 / 12168

页数：3

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