Comparison of Structural Properties of Copper Deposits from Sulfate and Pyrophosphate Electrolytes

被引：3
|
作者：
Arslan, B. [1 ]
Ulgudur, N. [2 ]
Erdogan, M. [3 ]
Imamoglu, I. [2 ]
Karakaya, I. [1 ]
机构：
[1] Middle E Tech Univ, Dept Metall & Mater Eng, TR-06531 Ankara, Turkey
[2] Middle Tech Univ, Dept Environm Eng, Ankara, Turkey
[3] Yildirim Beyazit Univ, Dept Mat Engn, Ankara, Turkey
来源：
FUNDAMENTALS OF ELECTROCHEMICAL GROWTH - FROM UPD TO MICROSTRUCTURES 3 | 2014年 / 58卷 / 32期
关键词：
ELECTRODEPOSITION; BATH;
D O I：
10.1149/05832.0105ecst
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Aluminum is quite often plated to combine the advantages of the light metal with modified surface properties. In this study, copper strike electrodeposits obtained from cyanide and pyrophosphate strike baths were compared in terms of microstructure, and copper pyrophosphate strike was found to yield smoother deposits. Furthermore, about 50 m thick copper depositions on the strike plated aluminum surface, were prepared from acid copper sulfate and copper pyrophosphate electrolytes to compare structural properties of the deposits. Comparison and characterization of copper electrodeposits from copper sulfate and pyrophosphate electrolytes were performed by potentiometry, SEM, roughness, and XRD analyses. Smoother and finer grained copper deposits were obtained from pyrophosphate electrolyte especially at low current densities.
引用
收藏
页码：105 / 113
页数：9
相关论文
共 50 条
  • [21] The influence of nickel ions on the long period electrowinning of zinc from sulfate electrolytes
    Zhang, Huaiwei
    Li, Yong
    Wang, Jikun
    Hong, Xin
    HYDROMETALLURGY, 2009, 99 (1-2) : 127 - 130
  • [22] Copper electrodeposition under a weak magnetic field: effect on the texturing and properties of the deposits
    Kovalyov, S. V.
    Girin, O. B.
    Debiemme-Chouvy, C.
    Mishchenko, V. I.
    JOURNAL OF APPLIED ELECTROCHEMISTRY, 2021, 51 (02) : 235 - 243
  • [23] Copper electrodeposition under a weak magnetic field: effect on the texturing and properties of the deposits
    S. V. Kovalyov
    O. B. Girin
    C. Debiemme-Chouvy
    V. I. Mishchenko
    Journal of Applied Electrochemistry, 2021, 51 : 235 - 243
  • [24] Mechanism for Codeposition of Multiwalled Carbon Nanotubes with Copper from Acid Copper Sulfate Bath
    Arai, Susumu
    Kato, Akihiro
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2013, 160 (09) : D380 - D385
  • [25] Structural Features of Ni-W Alloy Deposited from Pyrophosphate Electrolyte
    Krasikov, A. V.
    Krasikov, V. L.
    Markov, M. A.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2020, 93 (11) : 1688 - 1695
  • [26] EFFECT OF TETRABORATE IONS ON ELECTRODEPOSITION OF NICKEL-COPPER ALLOY FROM A PYROPHOSPHATE BATH
    ISHIKAWA, M
    ENOMOTO, H
    MATSUOKA, M
    IWAKURA, C
    ELECTROCHIMICA ACTA, 1994, 39 (14) : 2153 - 2157
  • [27] Magnetic and Structural Properties of Electrodeposited Iron on Copper and Silver
    K. Kömpe
    E. Kühl
    K. Nagorny
    Hyperfine Interactions, 2002, 141-142 : 419 - 424
  • [28] Electrochemical growth of copper nanoparticles: Structural and optical properties
    Mandke, Mohanrao V.
    Pathan, Habib M.
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2012, 686 : 19 - 24
  • [29] Magnetic and structural properties of electrodeposited iron on copper and silver
    Kömpe, K
    Kühl, E
    Nagorny, K
    HYPERFINE INTERACTIONS, 2002, 141 (1-4): : 419 - 424
  • [30] KINETICS AND MECHANISM OF REDUCTION OF THE IONS COPPER (II) FROM DIMETHYLSULPHOXIDE ELECTROLYTES
    Mamyrbekova, A. K.
    Serikbayeva, A. M.
    Mamyrbekova, A. K.
    BULLETIN OF THE NATIONAL ACADEMY OF SCIENCES OF THE REPUBLIC OF KAZAKHSTAN, 2014, (05): : 94 - 97
12345