Highly chemoselective 2,4,5-triaryl-1,3-dioxolane formation from intermolecular 1,3-dipolar addition of carbonyl ylide with aryl aldehydes

被引：50
作者：
Lu, CD [1 ]
Chen, ZY
Liu, H
Hu, WH
Mi, AQ
机构：
[1] Chinese Acad Sci, Key Lab Asymmet Synth & Chirotechnol Sichuan Prov, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing, Peoples R China
来源：
ORGANIC LETTERS | 2004年 / 6卷 / 18期
关键词：
D O I：
10.1021/ol0489494
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Rhodium(II) acetate catalyzed 1,3-dipolar cycloaddition of methyl phenyidiazoacetate with a mixture of electron-rich and electron-deficient aryl aldehydes gave 1,3-dioxolanes in high yield with excellent chemoselectivity.
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页码：3071 / 3074
页数：4
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