Stable Hydrogen-Bonding Complexes of Poly(4-vinylpyridine) and Polydiacetylenes for Photolithography and Sensing

被引：59

作者：

Wu, Si ^{[1
,2
]}

Shi, Feng ^{[2
]}

Zhang, Qijin ^{[1
]}

Bubeck, Christoph ^{[2
]}

机构：

[1] Univ Sci & Technol China, CAS Key Lab Soft Matter Chem, Dept Polymer Sci & Engn, Key Lab Optoelect Sci & Technol Anhui Prov, Hefei 230026, Anhui, Peoples R China

[2] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

来源：

MACROMOLECULES | 2009年 / 42卷 / 12期

基金：

中国国家自然科学基金;

关键词：

INDUCED CHROMATIC TRANSITION; LANGMUIR-BLODGETT-FILMS; SIDE-CHAIN POLYMERS; CONJUGATED POLYMER; SINGLE-CRYSTAL; TOPOCHEMICAL POLYMERIZATION; COLORIMETRIC REVERSIBILITY; MOLECULAR ARCHITECTURE; ORIENTED SYSTEMS; RATIONAL DESIGN;

D O I：

10.1021/ma9001929

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We prepare hydrogen-bonding complexes of the diacetylene derivatives 10,12-tricosadiynoic acid, 4,6-heptadecadiynoic acid, and ((E)-4-((4-(tricosa-10, 12-diynoyloxy)phenyl)diazenyl)benzoic acid and poly(4-vinylpyridine) in organic solvents. The complexes are spin-cast and form high-quality thin films, which can be photopolymerized and yield the blue phase of polydiacetylenes. A cross-linked network of the hydrogen-bonding complex is formed and shows improved stability to organic solvents. We demonstrate sensor capabilities for various organic solvents and gases by means of the blue-to-red color changes of polydiacetylenes. Based on the different solubility of the hydrogen-bonding complex before and after UV irradiation, photolithography can be employed to fabricate microstructures for polydiacetylene-based devices.

引用

页码：4110 / 4117

页数：8

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