ALD grown bilayer junction of ZnO:Al and tunnel oxide barrier for SIS solar cell

被引:23
作者
Bethge, O. [1 ]
Nobile, M. [1 ]
Abermann, S. [2 ]
Glaser, M. [1 ]
Bertagnolli, E. [1 ]
机构
[1] Vienna Univ Technol, Inst Solid State Elect, A-1040 Vienna, Austria
[2] Austrian Inst Technol, Dept Energy, A-1210 Vienna, Austria
基金
奥地利科学基金会;
关键词
SIS solar cell; AZO; Tunnel barrier; Metal oxides; ALD; XPS; THIN-FILMS; TRANSPARENT; PHOTOLUMINESCENCE; SPECTROSCOPY; DEPOSITION;
D O I
10.1016/j.solmat.2013.04.028
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Various metal oxides are probed as extrinsic thin tunnel barriers in Semiconductor Insulator Semiconductor solar cells. Namely Al2O3, ZrO2, Y2O3, and La2O3 thin films are in between n-type ZnO:Al (AZO) and p-type Si substrates by means of Atomic Layer Deposition. Low reverse dark current-density as low as 3 x 10(-7) A/cm(2), a fill factor up to 71.3%, and open-circuit voltage as high as 527 mV are obtained, achieving conversion efficiency of 8% for the rare earth oxide La2O3. ZrO2 and notably Al2O3 show drawbacks in performance suggesting an adverse reactivity with AZO as also indicated by X-ray Photoelectron Spectroscopy. (C) 2013 The Authors. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:178 / 182
页数:5
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