Cross-linkable azido C60-fullerene derivatives for efficient thermal stabilization of polymer bulk-heterojunction solar cells

被引:32
作者
Diacon, Aurel [1 ]
Derue, Lionel [2 ]
Lecourtier, Clemence [2 ,3 ]
Dautel, Olivier [4 ]
Wantz, Guillaume [2 ]
Hudhomme, Pietrick [1 ]
机构
[1] Univ Angers, Lab MOLTECH Anjou, UMR CNRS 6200, F-49045 Angers, France
[2] Univ Bordeaux, Lab IMS, UMR CNRS 5218, Ecole Natl Super Chim Biol & Phys, F-33607 Pessac, France
[3] Lab LOF, F-33608 Pessac, France
[4] Ecole Natl Super Chim Montpellier, UMR CNRS 5253, Inst Charles Gerhardt Montpellier, Lab AM2N, F-34296 Montpellier 5, France
关键词
MORPHOLOGICAL STABILIZATION; ORGANIC PHOTOVOLTAICS; HIGHLY EFFICIENT; PERFORMANCE; STABILITY; ENHANCEMENT; BISADDUCT; ACCEPTORS; NETWORK;
D O I
10.1039/c4tc01178c
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Original [60]PCBM-inspired fullerene derivatives bearing an azido functional group were synthesized. By incorporating an optimized quantity of this thermal cross-linker additive in the P3HT:[60]PCBM photoactive layer, an impressive stabilization of the bulk-heterojunction morphology at its optimal photovoltaic performance was achieved.
引用
收藏
页码:7163 / 7167
页数:5
相关论文
共 52 条
[41]   Efficiency enhancement in low-bandgap polymer solar cells by processing with alkane dithiols [J].
Peet, J. ;
Kim, J. Y. ;
Coates, N. E. ;
Ma, W. L. ;
Moses, D. ;
Heeger, A. J. ;
Bazan, G. C. .
NATURE MATERIALS, 2007, 6 (07) :497-500
[42]   "Plastic" Solar Cells: Self-Assembly of Bulk Heterojunction Nanomaterials by Spontaneous Phase Separation [J].
Peet, Jeffrey ;
Heeger, Alan J. ;
Bazan, Guillermo C. .
ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) :1700-1708
[43]   The Role of Processing in the Fabrication and Optimization of Plastic Solar Cells [J].
Peet, Jeffrey ;
Senatore, Michelle L. ;
Heeger, Alan J. ;
Bazan, Guillermo C. .
ADVANCED MATERIALS, 2009, 21 (14-15) :1521-1527
[44]   Polymer Solar Cells: Recent Approaches and Achievements [J].
Po, Riccardo ;
Maggini, Michele ;
Camaioni, Nadia .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (02) :695-706
[45]   ADDITION OF AZIDES TO C-60 - SYNTHESIS OF AZAFULLEROIDS [J].
PRATO, M ;
LI, QC ;
WUDL, F ;
LUCCHINI, V .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (03) :1148-1150
[46]   A Mechanistic Understanding of Processing Additive-Induced Efficiency Enhancement in Bulk Heterojunction Organic Solar Cells [J].
Schmidt, Kristin ;
Tassone, Christopher J. ;
Niskala, Jeremy R. ;
Yiu, Alan T. ;
Lee, Olivia P. ;
Weiss, Thomas M. ;
Wang, Cheng ;
Frechet, Jean M. J. ;
Beaujuge, Pierre M. ;
Toney, Michael F. .
ADVANCED MATERIALS, 2014, 26 (02) :300-305
[47]   Itraconazole Side Chain Analogues: Structure-Activity Relationship Studies for Inhibition of Endothelial Cell Proliferation, Vascular Endothelial Growth Factor Receptor 2 (VEGFR2) Glycosylation, and Hedgehog Signaling [J].
Shi, Wei ;
Nacev, Benjamin A. ;
Aftab, Blake T. ;
Head, Sarah ;
Rudin, Charles M. ;
Lie, Jun O. .
JOURNAL OF MEDICINAL CHEMISTRY, 2011, 54 (20) :7363-7374
[48]   Organic photovoltaics -: Polymer-fullerene composite solar cells [J].
Thompson, Barry C. ;
Frechet, Jean M. J. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (01) :58-77
[49]   Stabilizing polymer-based bulk heterojunction solar cells via crosslinking [J].
Wantz, Guillaume ;
Derue, Lionel ;
Dautel, Olivier ;
Rivaton, Agnes ;
Hudhomme, Pietrick ;
Dagron-Lartigau, Christine .
POLYMER INTERNATIONAL, 2014, 63 (08) :1346-1361
[50]   "Clicked" fluoropolymer elastomers as robust materials for potential microfluidic device applications [J].
Yang, Ying-Wei ;
Hentschel, Jens ;
Chen, Yi-Chun ;
Lazari, Mark ;
Zeng, Hanxiang ;
van Dam, R. Michael ;
Guan, Zhibin .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (03) :1100-1106