Cross-linkable azido C60-fullerene derivatives for efficient thermal stabilization of polymer bulk-heterojunction solar cells

被引:32
作者
Diacon, Aurel [1 ]
Derue, Lionel [2 ]
Lecourtier, Clemence [2 ,3 ]
Dautel, Olivier [4 ]
Wantz, Guillaume [2 ]
Hudhomme, Pietrick [1 ]
机构
[1] Univ Angers, Lab MOLTECH Anjou, UMR CNRS 6200, F-49045 Angers, France
[2] Univ Bordeaux, Lab IMS, UMR CNRS 5218, Ecole Natl Super Chim Biol & Phys, F-33607 Pessac, France
[3] Lab LOF, F-33608 Pessac, France
[4] Ecole Natl Super Chim Montpellier, UMR CNRS 5253, Inst Charles Gerhardt Montpellier, Lab AM2N, F-34296 Montpellier 5, France
关键词
MORPHOLOGICAL STABILIZATION; ORGANIC PHOTOVOLTAICS; HIGHLY EFFICIENT; PERFORMANCE; STABILITY; ENHANCEMENT; BISADDUCT; ACCEPTORS; NETWORK;
D O I
10.1039/c4tc01178c
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Original [60]PCBM-inspired fullerene derivatives bearing an azido functional group were synthesized. By incorporating an optimized quantity of this thermal cross-linker additive in the P3HT:[60]PCBM photoactive layer, an impressive stabilization of the bulk-heterojunction morphology at its optimal photovoltaic performance was achieved.
引用
收藏
页码:7163 / 7167
页数:5
相关论文
共 52 条
[31]   Fullerene bisadducts for enhanced open-circuit voltages and efficiencies in polymer solar cells [J].
Lenes, Martijn ;
Wetzelaer, Gert-Jan A. H. ;
Kooistra, Floris B. ;
Veenstra, Sjoerd C. ;
Hummelen, Jan C. ;
Blom, Paul W. M. .
ADVANCED MATERIALS, 2008, 20 (11) :2116-+
[32]   Functional fullerenes for organic photovoltaics [J].
Li, Chang-Zhi ;
Yip, Hin-Lap ;
Jen, Alex K. -Y. .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (10) :4161-4177
[33]   Fullerene-Bisadduct Acceptors for Polymer Solar Cells [J].
Li, Yongfang .
CHEMISTRY-AN ASIAN JOURNAL, 2013, 8 (10) :2316-2328
[34]   Fullerene Nucleating Agents: A Route Towards Thermally Stable Photovoltaic Blends [J].
Lindqvist, Camilla ;
Bergqvist, Jonas ;
Feng, Ching-Chiao ;
Gustafsson, Stefan ;
Backe, Olof ;
Treat, Neil D. ;
Bounioux, Celine ;
Henriksson, Patrik ;
Kroon, Renee ;
Wang, Ergang ;
Sanz-Velasco, Anke ;
Kristiansen, Per Magnus ;
Stingelin, Natalie ;
Olsson, Eva ;
Inganas, Olle ;
Andersson, Mats R. ;
Muller, Christian .
ADVANCED ENERGY MATERIALS, 2014, 4 (09)
[35]   Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology [J].
Ma, WL ;
Yang, CY ;
Gong, X ;
Lee, K ;
Heeger, AJ .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (10) :1617-1622
[36]   P3HT:PCBM, Best Seller in Polymer Photovoltaic Research [J].
Minh Trung Dang ;
Hirsch, Lionel ;
Wantz, Guillaume .
ADVANCED MATERIALS, 2011, 23 (31) :3597-3602
[37]   Morphological Stabilization of Polymer Photovoltaic Cells by Using Cross-Linkable Poly(3-(5-hexenyl)thiophene) [J].
Miyanishi, Shoji ;
Tajima, Keisuke ;
Hashimoto, Kazuhito .
MACROMOLECULES, 2009, 42 (05) :1610-1618
[38]   Photo-Cross-Linkable Azide-Functionalized Polythiophene for Thermally Stable Bulk Heterojunction Solar Cells [J].
Nam, Chang-Yong ;
Qin, Yang ;
Park, Young S. ;
Hlaing, Htay ;
Lu, Xinhui ;
Ocko, Benjamin M. ;
Black, Charles T. ;
Grubbs, Robert B. .
MACROMOLECULES, 2012, 45 (05) :2338-2347
[39]   Business, market and intellectual property analysis of polymer solar cells [J].
Nielsen, Torben D. ;
Cruickshank, Craig ;
Foged, Soren ;
Thorsen, Jesper ;
Krebs, Frederik C. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2010, 94 (10) :1553-1571
[40]   Effects of postproduction treatment on plastic solar cells [J].
Padinger, F ;
Rittberger, RS ;
Sariciftci, NS .
ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (01) :85-88