Cross-linkable azido C60-fullerene derivatives for efficient thermal stabilization of polymer bulk-heterojunction solar cells

被引：32

作者：

Diacon, Aurel ^{[1
]}

Derue, Lionel ^{[2
]}

Lecourtier, Clemence ^{[2
,3
]}

Dautel, Olivier ^{[4
]}

Wantz, Guillaume ^{[2
]}

Hudhomme, Pietrick ^{[1
]}

机构：

[1] Univ Angers, Lab MOLTECH Anjou, UMR CNRS 6200, F-49045 Angers, France

[2] Univ Bordeaux, Lab IMS, UMR CNRS 5218, Ecole Natl Super Chim Biol & Phys, F-33607 Pessac, France

[3] Lab LOF, F-33608 Pessac, France

[4] Ecole Natl Super Chim Montpellier, UMR CNRS 5253, Inst Charles Gerhardt Montpellier, Lab AM2N, F-34296 Montpellier 5, France

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2014年 / 2卷 / 35期

关键词：

MORPHOLOGICAL STABILIZATION; ORGANIC PHOTOVOLTAICS; HIGHLY EFFICIENT; PERFORMANCE; STABILITY; ENHANCEMENT; BISADDUCT; ACCEPTORS; NETWORK;

D O I：

10.1039/c4tc01178c

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Original [60]PCBM-inspired fullerene derivatives bearing an azido functional group were synthesized. By incorporating an optimized quantity of this thermal cross-linker additive in the P3HT:[60]PCBM photoactive layer, an impressive stabilization of the bulk-heterojunction morphology at its optimal photovoltaic performance was achieved.

引用

页码：7163 / 7167

页数：5

共 52 条

[1] Dendrite growth in annealed polymer blends for use in bulk heterojunction solar cells [J].

Akogwu, Onobu ;

Akande, Wali ;

Tong, Tiffany ;

Soboyejo, Wole .

JOURNAL OF APPLIED PHYSICS, 2011, 110 (10)

[2] Economic assessment of solar electricity production from organic-based photovoltaic modules in a domestic environment [J].

Azzopardi, Brian ;

Emmott, Christopher J. M. ;

Urbina, Antonio ;

Krebs, Frederik C. ;

Mutale, Joseph ;

Nelson, Jenny .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (10) :3741-3753

[3] Improved thermal stability of bulk heterojunctions based on side-chain functionalized poly(3-alkylthiophene) copolymers and PCBM [J].

Bertho, Sabine ;

Campo, Bert ;

Piersimoni, Fortunato ;

Spoltore, Donato ;

D'Haen, Jan ;

Lutsen, Laurence ;

Maes, Wouter ;

Vanderzande, Dirk ;

Manca, Jean .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2013, 110 :69-76

[4] Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].

Brabec, Christoph J. ;

Gowrisanker, Srinivas ;

Halls, Jonathan J. M. ;

Laird, Darin ;

Jia, Shijun ;

Williams, Shawn P. .

ADVANCED MATERIALS, 2010, 22 (34) :3839-3856

[5]

Brabec CJ, 2001, ADV FUNCT MATER, V11, P15, DOI 10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO

[6]

2-A

[7] Organic electronics from perylene to organic photovoltaics: painting a brief history with a broad brush [J].

Brunetti, Fulvio G. ;

Kumar, Rajeev ;

Wudl, Fred .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (15) :2934-2948

[8] Mechanism of the addition reaction of alkyl azides to [60]fullerene and the subsequent N2 extrusion to form monoimino-[60]fullerenes [J].

Cases, M ;

Duran, M ;

Mestres, J ;

Martín, N ;

Solà, M .

JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (02) :433-442

[9] Enhanced Performance and Stability of a Polymer Solar Cell by Incorporation of Vertically Aligned, Cross-Linked Fullerene Nanorods [J].

Chang, Chih-Yu ;

Wu, Cheng-En ;

Chen, Shih-Yung ;

Cui, Chaohua ;

Cheng, Yen-Ju ;

Hsu, Chain-Shu ;

Wang, Yuh-Lin ;

Li, Yongfang .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (40) :9386-9390

[10] Materials for the Active Layer of Organic Photovoltaics: Ternary Solar Cell Approach [J].

Chen, Yung-Chung ;

Hsu, Chih-Yu ;

Lin, Ryan Yeh-Yung ;

Ho, Kuo-Chuan ;

Lin, Jiann T. .

CHEMSUSCHEM, 2013, 6 (01) :20-35

← 1 2 3 4 5 6 →