Carbon monoxide inside an open-cage fullerene

被引：81
作者：
Iwamatsu, Sho-ichi [1 ]
Stanisky, Christopher M.
Cross, R. James
Saunders, Martin
Mizorogi, Naomi
Nagase, Shigeru
Murata, Shizuaki
机构：
[1] Nagoya Univ, Grad Sch Environm Studies, Chikusa Ku, Nagoya, Aichi 4648601, Japan
[2] Yale Univ, Dept Chem, New Haven, CT 06520 USA
[3] Inst Mol Sci, Okazaki, Aichi 4448585, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 32期
关键词：
cage compounds; fullerenes; host-guest systems; inclusion compounds; nanostructures;
D O I：
10.1002/anie.200601241
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Inside the ball: An endohedral carbon monoxide complex of an open-cage derivative of a [60]fullerene is prepared by insertion of CO through the opening. The incorporation of CO within the C60 cage is confirmed by mass spectrometry as well as 13C NMR and IR spectroscopic studies. The product releases CO under ambient conditions to recover a mixture of the endohedral water complex and the empty cage. (Chemical Equation Presented). © 2006 Wiley-VCH Verlag GmbH &. Co. KGaA.
引用
收藏
页码：5337 / 5340
页数：4
相关论文
共 34 条
[1]   Interaction energies and NMR chemical shifts of noble gases in C-60 [J].
Buhl, M ;
Patchkovskii, S ;
Thiel, W .
CHEMICAL PHYSICS LETTERS, 1997, 275 (1-2) :14-18
[2]   SYNTHESIS OF PURE C-13(60) AND DETERMINATION OF THE ISOTOPE EFFECT FOR FULLERENE SUPERCONDUCTORS [J].
CHEN, CC ;
LIEBER, CM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (08) :3141-3142
[3]   Spherical aromaticity: Recent work on fullerenes, polyhedral boranes, and related structures [J].
Chen, ZF ;
King, RB .
CHEMICAL REVIEWS, 2005, 105 (10) :3613-3642
[4]   ENDOHEDRAL CHEMISTRY - ELECTRONIC-STRUCTURES OF MOLECULES TRAPPED INSIDE THE C60 CAGE [J].
CIOSLOWSKI, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (11) :4139-4141
[5]   A discrete metallocyclic complex that retains its solvent-templated channel structure on guest removal to yield a porous, gas sorbing material [J].
Dobrzanska, L ;
Lloyd, GO ;
Raubenheimer, HG ;
Barbour, LJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (38) :13134-13135
[6]   Surface heterogeneity of C-60 as studied by infrared spectroscopy of adsorbed CO and adsorption potential calculations [J].
Folman, M ;
Fastow, M ;
Kozirovski, Y .
LANGMUIR, 1997, 13 (05) :1118-1122
[7]  
HernandezRojas J, 1997, INT J QUANTUM CHEM, V65, P655, DOI 10.1002/(SICI)1097-461X(1997)65:5<655::AID-QUA32>3.0.CO
[8]  
2-Z
[9]  
HIRSCH A, 2005, FULLERENES CHEM REAC, P345
[10]   An infrared study on CO intercalated in solid C60 [J].
Holleman, I ;
von Helden, G ;
van der Avoird, A ;
Meijer, G .
JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (04) :2129-2139
1234