Magnetic CoFe2O4 Nanoparticles as an Efficient Catalyst for the Oxidation of Alcohols to Carbonyl Compounds in the Presence of Oxone as an Oxidant

被引：48

作者：

Sadri, Fariba ^{[1
]}

Ramazani, Ali ^{[2
]}

Massoudi, Abdolhossain ^{[1
]}

Khoobi, Mehdi ^{[3
]}

Azizkhani, Vahid ^{[2
]}

Tarasi, Roghayeh ^{[2
]}

Dolatyari, Leila ^{[4
]}

Min, Bong-Ki ^{[5
]}

机构：

[1] Payame Noor Univ, Dept Chem, Tehran, Iran

[2] Univ Zanjan, Dept Chem, Zanjan, Iran

[3] Univ Tehran Med Sci, Pharmaceut Sci Res Ctr, Tehran 14176, Iran

[4] Islamic Azad Univ, Dept Chem, Zanjan Branch, Zanjan, Iran

[5] Yeungnam Univ, Ctr Res Facil, Kyongsan 712749, South Korea

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2014年 / 35卷 / 07期

关键词：

Magnetic nanoparticles; Cobalt ferrite; Oxidation; Alcohols; Oxone; PEROXYMONOSULFATE; ACID; DEGRADATION; WATER; IRON;

D O I：

10.5012/bkcs.2014.35.7.2029

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Magnetically nano-CoFe2O4 efficiently catalyzes oxidation of primary and secondary benzylic and aliphatic alcohols to give the corresponding carbonyl products in good yields. The reactions were carried out in an aqueous medium at room temperature in the presence of oxone (potassium hydrogen monopersulfate) as an oxidant. In addition, the catalysts could be reused up to 6 runs without significant loss of activities. Catalyst was characterized by SEM, XRD and IR.

引用

页码：2029 / 2032

页数：4

共 30 条

[1] Degradation of organic contaminants in water with sulfate radicals generated by the conjunction of peroxymonosulfate with cobalt [J].