Sequential Introduction of Carbon Nucleophiles onto Silicon Atoms Using Methyl as a Leaving Group

被引：13

作者：

Horie, Hiroaki ^{[1
]}

Kajita, Yuichi ^{[1
]}

Matsubara, Seijiro ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Nishikyo Ku, Kyoto 6158510, Japan

来源：

CHEMISTRY LETTERS | 2009年 / 38卷 / 02期

关键词：

CROSS-COUPLING REACTION; SI-ME BOND; ORGANIC HALIDES; ALCOHOLS; CLEAVAGE; ALLYLSILANES; HYDROCARBON; GRIGNARD; SILANES; ALKENES;

D O I：

10.1246/cl.2009.116

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A molecular structure, which has a trimethylsilyl group in close proximity to a hydroxy group spatially, converts methyl on silicon into a good leaving group.

引用

页码：116 / 117

页数：2

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