Direct oxidative amidation of benzyl alcohols using EDTA@Cu(II) functionalized superparamagnetic nanoparticles

被引：46

作者：

Azizi, Kobra ^{[1
]}

Karimi, Meghdad ^{[1
]}

Nikbakht, Fatemeh ^{[1
]}

Heydari, Akbar ^{[1
]}

机构：

[1] Tarbiat Modares Univ, Dept Chem, Tehran, Iran

来源：

APPLIED CATALYSIS A-GENERAL | 2014年 / 482卷

关键词：

Benzyl alcohol; Amine; Oxidation; Amidation; Magnetic catalyst; AMINE HYDROCHLORIDE SALTS; ONE-POT SYNTHESIS; CATALYZED AMIDATION; AMIDE SYNTHESIS; ALDEHYDES; WATER; OXYGEN;

D O I：

10.1016/j.apcata.2014.06.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Superparamagnetic Fe3O4@EDTA-Cu(II) nanoparticles were readily prepared and identified as an effective catalyst for the tandem transformation of benzyl alcohols and amine hydrochloride salts into the corresponding amides with tert-butyl hydroperoxide (TBHP) as an oxidant. After completion of the reaction, the catalyst can be removed from the reaction vessel by assistance of an external magnet and reused at least six times without significant loss of its activity. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：336 / 343

页数：8

共 23 条

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