On the Chemistry of the Strong Organic Electron-Donor 1,2,4,5-Tetrakis(tetramethylguanidino)benzene: Electron Transfer in Donor-Acceptor Couples and Binuclear Late Transition Metal Complexes

被引：54

作者：

Peters, Anastasia ^{[1
]}

Trumm, Christine ^{[1
]}

Reinmuth, Matthias ^{[1
]}

Emeljanenko, Dimitri ^{[1
]}

Kaifer, Elisabeth ^{[1
]}

Himmel, Hans-Joerg ^{[1
]}

机构：

[1] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 25期

关键词：

Redox chemistry; N ligands; Electron transfer; Donor-acceptor systems; CHLORANILIC ACID; OXIDATION; REDOX;

D O I：

10.1002/ejic.200900399

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this work we report on some aspects of the chemistry of the organic electron-donor 1,2,4,5-tetrakis(tetramethylguanidino)benzene (ttmgb). Reactions with electron acceptors and proton donors as well as late transition metals to give binuclear complexes (including a binuclear Cu-II complex with antiferromagnetic coupling through the bridging ttmgb ligand) are analysed. These studies shed some light on the electron-donor/proton-acceptor and coordination behaviour of this compound. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：3791 / 3800

页数：10

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