Formation of bulk glassy Ni-(Co-)Nb-Ti-Zr alloys with high corrosion resistance

被引:42
作者
Pang, SJ [1 ]
Zhang, T [1 ]
Asami, K [1 ]
Inoue, A [1 ]
机构
[1] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan
关键词
bulk glassy alloy; nickel-based alloy; supercooled liquid region; corrosion;
D O I
10.2320/matertrans.43.1771
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
M60-xCoxNb20Ti10Zr10 (x = 0-40 at%) glassy alloys were formed by melt spinning and a large supercooled region of over 40 K for the 0-20at%Co alloys was found. The Ni60-xCoxNb20Ti10Zr10 (x = 0-20 at%) alloys have high glass-forming ability leading to the, formation of bulk glassy rods with diameters up to 1.5 mm by copper-mold casting. The bulk glassy alloys with 0-20 at%Co exhibited nearly the same anodic polarization behavior in 1N HCl solution. They were spontaneously passivated with a low passive current density of the order of 10(-2) A/m(2) and no pitting corrosion due to anodic polarization with a potential sweeping up to 2.0 V vs. Ag/AgCl occurred, indicating their high corrosion resistance in the aggressive acid.
引用
收藏
页码:1771 / 1773
页数:3
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