Multifunctional epoxy coatings combining a mixture of traps and inhibitor loaded nanocontainers for corrosion protection of AA2024-T3

被引:72
作者
Kartsonakis, I. A. [1 ,2 ]
Athanasopoulou, E. [1 ]
Snihirova, D. [3 ]
Martins, B. [3 ]
Koklioti, M. A. [1 ]
Montemor, M. F. [3 ]
Kordas, G. [2 ]
Charitidis, C. A. [1 ]
机构
[1] Natl Tech Univ Athens, Sch Chem Engn, GR-15780 Athens, Greece
[2] NCSR Demokritos, Inst Nanosci & Nanotechnol, Aghia Paraskevi 15310, Greece
[3] Univ Lisbon, ICEMS, Inst Super Tecn, DEQ, P-1049001 Lisbon, Portugal
关键词
Aluminium; Alloy; Organic coatings; EIS; SEM; ALUMINUM-ALLOYS; 8-HYDROXYQUINOLINE; NANOINDENTATION; CONTAINERS; ABILITY;
D O I
10.1016/j.corsci.2014.04.009
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This work aims at investigating the corrosion protection effectiveness of multifunctional epoxy coatings modified with pigments such as ceramic nanocontainers loaded with corrosion inhibitor, chloride and water traps, applied on AA2024-T3. Characterizations on the morphology, composition and structure of the coatings were conducted. The corrosion resistance was studied by electrochemical impedance spectroscopy, localized electrochemical impedance spectroscopy and scanning vibrating electrode technique. The mechanical behaviour of the coatings was examined through nanoindentation and nanoscratching tests. Electrochemical and nanomechanical testing results, evidenced the improvement of the corrosion protective properties and mechanical behaviour of the coatings in the presence of the various pigments. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:147 / 159
页数:13
相关论文
共 60 条
[1]   Chromium [J].
Barceloux, DG .
JOURNAL OF TOXICOLOGY-CLINICAL TOXICOLOGY, 1999, 37 (02) :173-194
[2]   THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].
BARRETT, EP ;
JOYNER, LG ;
HALENDA, PP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380
[3]   Influence of indenter tip geometry on elastic deformation during nanoindentation [J].
Bei, H ;
George, EP ;
Hay, JL ;
Pharr, GM .
PHYSICAL REVIEW LETTERS, 2005, 95 (04)
[4]  
BOYER R, 2006, CONCISE ENCY COMPOSI
[5]  
Brinker C. J., 2013, SOL GEL SCI PHYS CHE, DOI [DOI 10.1016/B978-0-08-057103-4.50001-5, 10.1016/C2009-0-22386-5]
[6]   Adsorption of gases in multimolecular layers [J].
Brunauer, S ;
Emmett, PH ;
Teller, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319
[7]  
Buchheit R.G., 2000, Surface Conversion for Aluminum and Ferrous Alloys, P67
[8]   Nanomechanical and nanotribological properties of carbon-based thin films: A review [J].
Charitidis, C. A. .
INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2010, 28 (01) :51-70
[9]  
CHARITIDIS CA, 2011, J NANOSTRUCT POLYM N, V7, P32
[10]   What is indentation hardness? [J].
Cheng, YT ;
Cheng, CM .
SURFACE & COATINGS TECHNOLOGY, 2000, 133 :417-424