Bis(μ-biphenyl-2,2′-dicarboxylato)bis[(2,2′-bipyridine)copper(II)]

被引：2
|
作者：
An, Zhe [1 ]
Cui, Rui-Hai [2 ]
Zhou, Ru-Jin [1 ]
机构：
[1] Maoming Univ, Sch Chem & Life Sci, Maoming 525000, Peoples R China
[2] Harbin Univ, Sch Chem & Life Sci, Harbin 150080, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
D O I：
10.1107/S1600536809008976
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Cu-2(C14H8O4)(2)(C10H8N2)(2)], was obtained by solvothermal synthesis. The Cu-II atom is coordinated by one chelating 2,2'-bipyridine ligand and two carboxyl groups from different biphenyl-2,2'-dicarboxylate ligands, leading to a distorted octahedral environment. Each carboxylate group makes one short Cu-O bond [1.9608 (14) and 1.9701 (14) angstrom] and one longer Cu-O contact [2.4338 (17) and 2.5541 (17) angstrom] to each Cu-II atom. The biphenyl-2,2'-dicarboxylate ligands bridge between Cu-II atoms, forming a dinuclear complex around a crystallographic inversion centre.
引用
收藏
页码：M412 / U631
页数：9
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