Abundant Metals Give Precious Hydrogenation Performance

被引:244
|
作者
Bullock, R. Morris [1 ]
机构
[1] Pacific NW Natl Lab, Ctr Mol Electrocatalysis, Richland, WA 99352 USA
关键词
ASYMMETRIC TRANSFER HYDROGENATION; IRON; CATALYSIS; MECHANISM;
D O I
10.1126/science.1247240
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Iron- or cobalt-based catalysts have outperformed traditional precious metal catalysts in several hydrogenation reactions.
引用
收藏
页码:1054 / 1055
页数:2
相关论文
共 50 条
  • [41] Hydrogenation of CO2 to formic acid over a non-precious metal-based polymeric catalyst
    Dabas, Shilpa
    Barik, Manas
    Rathour, Parul
    Biradar, Ankush V.
    Subramanian, Saravanan
    CHEMICAL COMMUNICATIONS, 2025, 61 (20) : 4022 - 4025
  • [42] Universal transition state scaling relations for (de)hydrogenation over transition metals
    Wang, S.
    Petzold, V.
    Tripkovic, V.
    Kleis, J.
    Howalt, J. G.
    Skulason, E.
    Fernandez, E. M.
    Hvolbaek, B.
    Jones, G.
    Toftelund, A.
    Falsig, H.
    Bjorketun, M.
    Studt, F.
    Abild-Pedersen, F.
    Rossmeisl, J.
    Norskov, J. K.
    Bligaard, T.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (46) : 20760 - 20765
  • [43] Recent Advances in the Sustainable Synthesis of Quinazolines Using Earth-Abundant First Row Transition Metals
    Zaib, Sumera
    Khan, Imtiaz
    CURRENT ORGANIC CHEMISTRY, 2020, 24 (15) : 1775 - 1792
  • [44] Manganese catalyzed transfer hydrogenation of biomass-derived aldehydes: Insights to the catalytic performance and mechanism
    Feng, Yunchao
    Long, Sishi
    Yan, Guihua
    Chen, Binglin
    Sperry, Jonathan
    Xu, Wanjie
    Sun, Yong
    Tang, Xing
    Zeng, Xianhai
    Lin, Lu
    JOURNAL OF CATALYSIS, 2020, 389 : 157 - 165
  • [45] Humic acids in brown coals from the southern Russian Far East: General characteristics and interactions with precious metals
    Avramenko, V. A.
    Bratskaya, S. Yu
    Yakushevich, A. S.
    Voit, A. V.
    Ivanov, V. V.
    Ivannikov, S. I.
    GEOCHEMISTRY INTERNATIONAL, 2012, 50 (05) : 437 - 446
  • [46] A quasi-stable molybdenum sub-oxide with abundant oxygen vacancies that promotes CO2 hydrogenation to methanol
    Kuwahara, Yasutaka
    Mihogi, Takashi
    Hamahara, Koji
    Kusu, Kazuki
    Kobayashi, Hisayoshi
    Yamashita, Hiromi
    CHEMICAL SCIENCE, 2021, 12 (29) : 9902 - 9915
  • [47] Chiral complexes of transition metals with chelating nitrogen ligands in asymmetric hydrogenation with hydrogen transfer
    Badyrova, Nataliya M.
    Nindakova, Lidiya O.
    IZVESTIYA VUZOV-PRIKLADNAYA KHIMIYA I BIOTEKHNOLOGIYA, 2019, 9 (04): : 621 - 634
  • [48] Insights into the Staggered Nature of Hydrogenation Reactivity over the 4d Transition Metals
    Crawford, Paul
    McAllister, Bronagh
    Hu, P.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (13) : 5222 - 5227
  • [49] Recent advances in homogeneous borrowing hydrogen catalysis using earth-abundant first row transition metals
    Reed-Berendt, Benjamin G.
    Polidano, Kurt
    Morrill, Louis C.
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2019, 17 (07) : 1595 - 1607
  • [50] Dipyrromethane-diphosphine: the effect of meso substituents on the formation of nickel complexes and on their performance in the transfer hydrogenation of ketones
    Gupta, Rohit
    Kumar, Ashok
    Mani, Ganesan
    DALTON TRANSACTIONS, 2023, 52 (48) : 18332 - 18341