Abundant Metals Give Precious Hydrogenation Performance

被引：246

作者：

Bullock, R. Morris ^{[1
]}

机构：

[1] Pacific NW Natl Lab, Ctr Mol Electrocatalysis, Richland, WA 99352 USA

来源：

SCIENCE | 2013年 / 342卷 / 6162期

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; IRON; CATALYSIS; MECHANISM;

D O I：

10.1126/science.1247240

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Iron- or cobalt-based catalysts have outperformed traditional precious metal catalysts in several hydrogenation reactions.

引用

页码：1054 / 1055

页数：2

共 15 条

[1] Asymmetric hydrogenation of unfunctionalized, purely alkyl-substituted olefins [J].

Bell, S ;

Wüstenberg, B ;

Kaiser, S ;

Menges, F ;

Netscher, T ;

Pfaltz, A .

SCIENCE, 2006, 311 (5761) :642-644

[2] A new iron age [J].

Bolm, Carsten .

NATURE CHEMISTRY, 2009, 1 (05) :420-420

[3]

Bullock R. M., 2010, Catalysis without Precious Metals

[4] Sustainable metal catalysis with iron: From rust to a rising star? [J].

Enthaler, Stephan ;

Junge, Kathrin ;

Beller, Matthias .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (18) :3317-3321

[5] Cobalt Precursors for High-Throughput Discovery of Base Metal Asymmetric Alkene Hydrogenation Catalysts [J].

Friedfeld, Max R. ;

Shevlin, Michael ;

Hoyt, Jordan M. ;

Krska, Shane W. ;

Tudge, Matthew T. ;

Chirik, Paul J. .

SCIENCE, 2013, 342 (6162) :1076-1080

[6] Nanoscale Fe2O3-Based Catalysts for Selective Hydrogenation of Nitroarenes to Anilines [J].

Jagadeesh, Rajenahally V. ;

Surkus, Annette-Enrica ;

Junge, Henrik ;

Pohl, Marga-Martina ;

Radnik, Joerg ;

Rabeah, Jabor ;

Huan, Heming ;

Schuenemann, Volker ;

Brueckner, Angelika ;

Beller, Matthias .

SCIENCE, 2013, 342 (6162) :1073-1076

[7] ASYMMETRIC HYDROGENATION OF METHYL-(Z)-ALPHA-ACETAMIDOCINNAMATE CATALYZED BY (1,2-BIS((PHENYL-ORTHO-ANISOYL)PHOSPHINO)ETHANE)RHODIUM(I) - KINETICS, MECHANISM, AND ORIGIN OF ENANTIOSELECTION [J].

LANDIS, CR ;

HALPERN, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (06) :1746-1754

[8] Powering the planet: Chemical challenges in solar energy utilization [J].

Lewis, Nathan S. ;

Nocera, Daniel G. .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2006, 103 (43) :15729-15735

[9] The Mechanism of Efficient Asymmetric Transfer Hydrogenation of Acetophenone Using an Iron(II) Complex Containing an (S,S)-Ph2PCH2CH=NCHPhCHPhN=CHCH2PPh2 Ligand: Partial Ligand Reduction Is the Key [J].

Mikhailine, Alexandre A. ;

Maishan, Mazharul I. ;

Lough, Alan J. ;

Morris, Robert H. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (29) :12266-12280

[10]

Noyori R, 2002, ANGEW CHEM INT EDIT, V41, P2008, DOI 10.1002/1521-3773(20020617)41:12<2008::AID-ANIE2008>3.0.CO

← 1 2 →