Efficient and Facile Method for the Nitration of Aromatic Compounds by Nitric Acid in Micellar Media

被引：23
|
作者：
Sana, S. [1 ]
Tasneem [1 ]
Ali, M. Moazzam [1 ]
Rajanna, K. C. [1 ]
Saiprakash, P. K. [2 ]
机构：
[1] Osmania Univ, Postgrad Coll, Mirzapur 502249 B, India
[2] Osmania Univ, Dept Chem, Hyderabad 500007, Andhra Pradesh, India
来源：
SYNTHETIC COMMUNICATIONS | 2009年 / 39卷 / 16期
关键词：
CTAB; efficient nitration of aromatic compounds; micellar media; SDS; Triton-X; 100;
D O I：
10.1080/00397910802711318
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Aromatic compounds were efficiently nitrated under mild reaction conditions by employing HNO3 in the presence of anionic (sodium dodecyl sulfate, SDS), cationic (cetyl trimethyl ammonium bromide, CTAB), and nonionic (Triton-X 100) micelles. The reaction rapidly afforded corresponding mononitro derivatives in fair to good yields with high regioselectivity. This new method offers an environmentally safe reaction condition to minimize the waste products.
引用
收藏
页码：2949 / 2953
页数：5
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