Preparation and photocatalytic properties of Fe-doped TiO2 nanoparticles

被引:20
作者
Chen, XQ [1 ]
Yang, JY [1 ]
Zhang, JS [1 ]
机构
[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
来源
JOURNAL OF CENTRAL SOUTH UNIVERSITY OF TECHNOLOGY | 2004年 / 11卷 / 02期
关键词
nanometer titanium dioxide; iron ion implantation; photocatalytic activity; paper-making wastewater;
D O I
10.1007/s11771-004-0033-2
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Nanocrystalline Fe-doped TiO2 with size of 60 - 70 nm was prepared by a sot-gel technique, followed by freeze-drying treatment for 2 h. Thermogravimetric and differential thermal analyses, X-ray diffraction, scanning electron microscope, laser diffraction particle size analyzer and UV-Vis spectrophotometer technologies were used to characterize the product. The photocatalytic activities of the samples were evaluated by the degradation of wastewater of paper-making. The effects of Fe ion implantation on the photocatatytic activity of TiO2 were also discussed. The results show that the iron content plays an essential role in affecting the photocatalytic activity of the Fe-doped TiO2 and the optimum content of Fe-doped is 0.05% (mass fraction). The photocatalytic activity of samples with lower content of Fe-doped is higher than that of pure TiO2 in the treatment of paper-making wastewater. The photo-degradation effect of paper-making effluent is the best by means of Fe-doped TiO2 with 0.05% Fe.
引用
收藏
页码:161 / 165
页数:5
相关论文
共 8 条
[1]  
HIROMI Y, 2001, J MATER CHEM, V11, P2537
[2]   ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS [J].
HOFFMANN, MR ;
MARTIN, ST ;
CHOI, WY ;
BAHNEMANN, DW .
CHEMICAL REVIEWS, 1995, 95 (01) :69-96
[3]   Photocatalytic properties of gold/gold ion-modified titanium dioxide for wastewater treatment [J].
Li, FB ;
Li, XZ .
APPLIED CATALYSIS A-GENERAL, 2002, 228 (1-2) :15-27
[4]  
MATSUMOTO Y, 2002, APPL SURF SCI, V189, P1
[5]   Phororedox and photocatalytic processes on Fe(III)-porphyrin surface modified nanocrystalline TiO2 [J].
Molinari, A ;
Amadelli, R ;
Antolini, L ;
Maldotti, A ;
Battioni, P ;
Mansuy, D .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 158 (02) :521-531
[6]  
VERONICA V, 2004, CATAL TODAY, V68, P201
[7]  
ZHANG YH, 2001, J MAT LETT, V51, P455
[8]   The chemical states and properties of doped TiO2 film photocatalyst prepared using the Sol-Gel method with TiCl4 as a precursor [J].
Zhu, YF ;
Zhang, L ;
Yao, WQ ;
Cao, LL .
APPLIED SURFACE SCIENCE, 2000, 158 (1-2) :32-37