Preyssler heteropolyacid supported on nano-SiO2, H14[NaP5W30O110]/SiO2: a green and reusable catalyst in the synthesis of polysubstituted quinolines

被引:0
作者
Gharib, A. [1 ,2 ]
Khorasani, B. R. Hashemipour [2 ]
Jahangir, M. [1 ]
Roshani, M. [1 ]
Bakhtiari, L. [2 ]
Mohadeszadeh, S. [2 ]
Ahmadi, S. [2 ]
机构
[1] Islamic Azad Univ, Dept Chem, Mashhad, Iran
[2] Agr Res & Serv Ctr, Mashhad, Iran
来源
BULGARIAN CHEMICAL COMMUNICATIONS | 2014年 / 46卷 / 02期
关键词
Nano-SiO2-supported; Preyssler; Heteropolyacids; Polysubstituted quinoline; Quinolines; Catalyst; EPSILON-CAPROLACTONE; HYDROGEN-PEROXIDE; RECENT PROGRESS; ACIDS; DERIVATIVES; OXIDATION; EFFICIENT; SOLVENT; KEGGIN; SALTS;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Synthesis of polysubstituted quinolines in the presence of silica-supported Preyssler nanoparticles (SPNP), H-14[NaP5W30O110]/SiO2, Preyssler H-14[NaP5W30O110] and Keggin heteropolyacids, H3PW12O40, 117[PMo8V4O40], H-6[PMo9V3O40], H-5[PMo10V2O40], H-4[PMo11VO40], H-3[PMo12O40] as catalyst under aqueous conditions is described. The best conditions were observed using Preyssler and silica-supported Preyssler nanoparticles as catalysts. The catalyst is recyclable and reusable.
引用
收藏
页码:223 / 232
页数:10
相关论文
共 39 条
[1]  
Aggrawal A. K., 1991, MACROMOLECULES, V24, P6806
[2]   A HETEROPOLYANION WITH FIVEFOLD MOLECULAR SYMMETRY THAT CONTAINS A NONLABILE ENCAPSULATED SODIUM-ION - THE STRUCTURE AND CHEMISTRY OF [NAP5W30O110]14- [J].
ALIZADEH, MH ;
HARMALKER, SP ;
JEANNIN, Y ;
MARTINFRERE, J ;
POPE, MT .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (09) :2662-2669
[3]   Effective direct esterification of butanol by eco-friendly Preyssler catalyst, [NaP5W30O110]14- [J].
Bamoharram, Fatemeh F. ;
Heravi, Majid M. ;
Roshani, Mina ;
Jahangir, Manouchehr ;
Gharib, Ali .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 271 (1-2) :126-130
[4]   N-oxidation of pyridine carboxylic acids using hydrogen peroxide catalyzed by a green heteropolyacid catalyst:: Preyssler's anion, [NaP5W30O110]14- [J].
Bamoharram, Fatemeh F. ;
Heravi, Majid M. ;
Roshani, Mina ;
Tavakoli, Niloofar .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 252 (1-2) :219-225
[5]   Preyssler catalyst,[NaP5W30O110]14- :: A green, efficient and reusable catalyst for esterification of salicylic acid with aliphatic and benzylic alcohols [J].
Bamoharram, FF ;
Heravi, MM ;
Roshani, M ;
Jahangir, M ;
Gharib, A .
APPLIED CATALYSIS A-GENERAL, 2006, 302 (01) :42-47
[6]   Heteropolyacid-based catalysis. Dawson acid for MTBE synthesis in gas phase [J].
Baronetti, G ;
Briand, L ;
Sedran, U ;
Thomas, H .
APPLIED CATALYSIS A-GENERAL, 1998, 172 (02) :265-272
[7]   A mild and efficient one-step synthesis of quinolines [J].
De, SK ;
Gibbs, RA .
TETRAHEDRON LETTERS, 2005, 46 (10) :1647-1649
[8]   Selective epoxidation of cyclohexene to cyclohexene oxide catalyzed by Keggin-type heteropoly compounds using anhydrous urea-hydrogen peroxide as oxidizing reagent and acetonitrile as the solvent [J].
Ding, Y ;
Gao, Q ;
Li, GX ;
Zhang, HP ;
Wang, JM ;
Yan, L ;
Suo, JS .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 218 (02) :161-170
[10]   Heteropoly acids, their salts and polyoxometalates as heterogenous, efficient and eco-friendly catalysts in organic reactions: Some recent advances [J].
Firouzabadi, H. ;
Jafari, A. A. .
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2005, 2 (02) :85-114