Behavior of [1,2,5]oxadiazolo[3,4-e][1,2,3,4]tetrazine 4,6-dioxide in various media

被引：19

作者：

Zelenov, V. P. ^{[1
]}

Lobanova, A. A. ^{[1
]}

Lyukshenko, N. I. ^{[1
]}

Sysolyatin, S. V. ^{[2
]}

Kalashnikov, A. I. ^{[1
,2
]}

机构：

[1] Fed Res & Prod Ctr Altai, Biysk Of Altai Krai 659322, Russia

[2] Russian Acad Sci, Siberian Branch, Inst Problems Chem & Energet Technol, Biysk Of Altai Krai 659322, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2008年 / 57卷 / 07期

关键词：

1,2,3,4-tetrazine 1,3-dioxides; 1,2,5]oxadiazolo[3,4-e][1,2,3,4]tetrazine 4,6-dioxide; hydrolysis; kinetic laws; triazolofurazans; activation energy; tautomerism;

D O I：

10.1007/s11172-008-0180-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A behavior of [1,2,5]oxadiazolo[3,4-e][1,2,3,4]tetrazine 4,6-dioxide (1) in organic solvents and aqueous solutions of various acidity has been studied by UV spectrophotometry. Kinetic laws for the N,N'-dioxide 1 hydrolysis have been established and decomposition process constants at various temperatures in the media with pH 6.86 have been determined. A product of the reaction with water, viz., 5H-[1,2,3]triazolo[4,5-c][1,2,5]oxadiazole, has been isolated. 5-(tert-Butyl)-5H-[1,2,3]triazolo[4,5-c][1,2,5]oxadiazole has been synthesized as the model compound. Decomposition of N,N'-dioxide 1 occurs in basic media.

引用

页码：1384 / 1389

页数：6

共 50 条

[1] Behavior of [1,2,5]oxadiazolo[3,4-e][1,2,3,4]tetrazine 4,6-dioxide in various media
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S. V. Sysolyatin
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Russian Chemical Bulletin, 2008, 57 : 1384 - 1389
[2] New syntheses of [1,2,5]oxadiazolo[3,4-e][1,2,3,4]tetrazine 4,6-dioxide
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[3] New syntheses of [1,2,5]oxadiazolo[3,4-e][1,2,3,4]tetrazine 4,6-dioxide
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