One-Pot Synthesis of Azobenzene Derivatives by Oxidation of 2,3-Dihydrobenzothiadiazines

被引：3

作者：

Cannazza, Giuseppe ^{[1
]}

Perrone, Serena ^{[2
]}

Rosato, Francesca ^{[2
]}

D'Accolti, Lucia ^{[3
]}

Parenti, Carlo ^{[1
]}

Troisi, Luigino ^{[2
]}

机构：

[1] Univ Modena & Reggio Emilia, Dipartimento Sci Vita, I-41125 Modena, Italy

[2] Univ Salento, Dipartimento Sci & Tecnol Biol & Ambientali, I-73100 Lecce, Italy

[3] Univ Bari Aldo Moro, Dipartimento Chim, I-70126 Bari, Italy

来源：

SYNTHESIS-STUTTGART | 2014年 / 46卷 / 07期

关键词：

azo compounds; sulfonamides; oxidation; ring opening; imines; ALLOSTERIC MODULATORS; STABILITY;

D O I：

10.1055/s-0033-1338587

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An oxidative route to N-substituted sulfonamidic azobenzene derivatives is reported. A mechanism, based on a rationalization of previous findings, is proposed. This simple one-pot method could be adapted to the synthesis of a range of substituted sulfonylazobenzenes with potential applications in the pharmaceutical and industrial fields.

引用

页码：962 / 966

页数：5