Electrochemical Performance of La2CuO4 Nanotube Materials Prepared via Electrospinning Method

被引:0
作者
Sun Li-Ping [1 ]
Zhao Hui [1 ]
Wang Wen-Xue [1 ]
Li Qiang [1 ]
Huo Li-Hua [1 ]
机构
[1] Heilongjiang Univ, Sch Chem & Mat Sci, Minist Educ, Key Lab Funct Inorgan Mat Chem, Harbin 150080, Peoples R China
关键词
La2CuO4; nanotubes; Intermediate temperature solid oxide fuel cell (ITSOFC); cathode materials; electrode reaction; OXIDE FUEL-CELLS; COMPOSITE CATHODES; TEMPERATURE; SOFC; NANOFIBER;
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
La2CuO4 nanotubes are successfully synthesized by electro-spinning technology. The structure and morphology of the materials are characterized by XRD, TG-DTA and SEM, respectively. The results show that La2CuO4 nanotubes with an average diameter of 150 nm are obtained after sintering at 700 degrees C for 2 h. The La2CuO4 nanotube forms sufficient connection with each other, and good contact with the electrolyte after sintering at 900 degrees C for 0.5 h. Comparing the results obtained by Electrochemical Impedance Spectroscopy (EIS), it is clearly observed that the nanotube cathode exhibits superior performance than the powder cathode. The area specific resistance (ASR) of the nanotube cathode is 1.03 Omega.cm(2) at 700 degrees C in air, whereas for the powder one with the same composition, the ASR is 1.61 Omega.cm(2). The oxygen partial pressure measurement indicates that the charge transfer process is the rate-limiting step of the nanotube electrode reactions.
引用
收藏
页码:757 / 762
页数:6
相关论文
共 25 条
  • [1] Electrochemical characterization of mixed conducting and composite SOFC cathodes
    Bebelis, S.
    Kotsionopoulos, N.
    Mai, A.
    Rutenbeck, D.
    Tietz, F.
    [J]. SOLID STATE IONICS, 2006, 177 (19-25) : 1843 - 1848
  • [2] Superconducting phase with Tc of 17 K in La2CuO4+δ
    Chen, L
    Dong, C
    Huang, YZ
    Zhou, F
    Che, GC
    Zhao, ZX
    [J]. SOLID STATE COMMUNICATIONS, 2000, 114 (02) : 107 - 111
  • [3] The direct decomposition of NO over the La2CUO4 nanofiber catalyst
    Gao, Lizhen
    Chua, Hui Tong
    Kawi, Sibudjing
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2008, 181 (10) : 2804 - 2807
  • [4] Investigation of oxygen reduction reaction kinetics on Sm0.5Sr0.5CoO3-δ cathode supported on Ce0.85Sm0.075Nd0.075O2-δ electrolyte
    Gao, Zhan
    Liu, Xingmin
    Bergman, Bill
    Zhao, Zhe
    [J]. JOURNAL OF POWER SOURCES, 2011, 196 (22) : 9195 - 9203
  • [5] Novel SrTixCo1-xO3-δ cathodes for low-temperature solid oxide fuel cells
    Gao, Zhan
    Mao, Zongqiang
    Wang, Cheng
    Liu, Zhixiang
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (12) : 7229 - 7233
  • [6] Observation of specific heat jump in La2CuO4.093 due to superconducting transition
    Hirayama, T
    Nakagawa, M
    Oda, Y
    [J]. SOLID STATE COMMUNICATIONS, 1999, 113 (03) : 121 - 124
  • [7] Development of solid oxide fuel cell materials for intermediate-to-low temperature operation
    Huang, Jianbing
    Xie, Fucheng
    Wang, Cheng
    Mao, Zongqiang
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (01) : 877 - 883
  • [8] Characterization of LSM-YSZ composite electrode by ac impedance spectroscopy
    Kim, JD
    Kim, GD
    Moon, JW
    Park, YI
    Lee, WH
    Kobayashi, K
    Nagai, M
    Kim, CE
    [J]. SOLID STATE IONICS, 2001, 143 (3-4) : 379 - 389
  • [9] Development of porous cathode powders for SOFC and influence of cathode structure on the oxygen electroreduction kinetics
    Kivi, I.
    Moller, P.
    Kurig, H.
    Kallip, S.
    Nurk, G.
    Lust, E.
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2008, 10 (10) : 1455 - 1458
  • [10] Improved electrochemical performance of Ca2Fe1.4Co0.6O5-Ce0.9Gd0.1O1.95 composite cathodes for intermediate-temperature solid oxide fuel cells
    Li, Qiang
    Sun, Liping
    Huo, Lihua
    Zhao, Hui
    Grenier, Jean-Claude
    [J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2012, 16 (03) : 1169 - 1174