Elimination of crystal violet from synthetic medium by adsorption using unmodified and acid-modified eucalyptus leaves with MPR and GA application

被引:45
作者
Ghosh, Koushik [1 ]
Bar, Nirjhar [1 ]
Biswas, Asit Baran [1 ]
Das, Sudip Kumar [1 ]
机构
[1] Univ Calcutta, Dept Chem Engn, 92 APC Rd, Kolkata 700009, India
关键词
Crystal violet; Acid-modified eucalyptus leaves; Kinetics model; Isotherm models; Genetic algorithm;
D O I
10.1016/j.scp.2020.100370
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The aim of this investigation concerns the elimination by batch adsorption method of a primary (cationic) textile dye (Crystal Violet) from the synthetic medium, using raw and acid-modified eucalyptus leaves. Parametric studies, such as pH (2-10), unmodified and acid-modified eucalyptus leaves dose (1-10 g L-1), time (5-300 min), and initial strength of CV (10-300 mg L-1) are performed on the elimination of Crystal Violet from the Synthetic Medium. The R-P model gives the maximum coefficient of correlation (R-2 = 0.99), which denotes the best fitting isotherms with the investigational data from the other isotherms. The maximal capacity of adsorption is 141 mg g(-1) for Crystal Violet (CV) on PEUL at 25 degrees C and pH7. The kinetics study of the CV elimination signifies the pseudo 2nd order kinetics model gives the acceptable fitting rate equation (R-2 = 0.99) with the investigational data. Intraparticle diffusion model, IPD implies it's not only the rate-limiting step. The overall outcome recommends eucalyptus leaves probably utilized as a low-cost environment-friendly adsorbent for the de-pollution of effluents laden with basic (cationic) textile dye (CV). MPR and GA application on experimental data correctly predicted the removal percentage.
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页数:12
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共 54 条
[1]   Dye sequestration using agricultural wastes as adsorbents [J].
Adegoke, Kayode Adesina ;
Bello, Olugbenga Solomon .
WATER RESOURCES AND INDUSTRY, 2015, 12 :8-24
[2]   Adsorption studies of hazardous malachite green onto treated ginger waste [J].
Ahmad, Rais ;
Kumar, Rajeev .
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2010, 91 (04) :1032-1038
[3]   Polymerization of graphene oxide with polystyrene: Non-linear isotherms and kinetics studies of anionic dyes [J].
Azizi, A. ;
Moniri, E. ;
Hassani, A. H. ;
Panahi, H. Ahmad ;
Miralinaghi, M. .
MICROCHEMICAL JOURNAL, 2019, 145 :559-565
[4]   A review of potentially low-cost sorbents for heavy metals [J].
Bailey, SE ;
Olin, TJ ;
Bricka, RM ;
Adrian, DD .
WATER RESEARCH, 1999, 33 (11) :2469-2479
[5]   Cr(VI) adsorption by a green adsorbent walnut shell: Adsorption studies, regeneration studies, scale-up design and economic feasibility [J].
Banerjee, Munmun ;
Basu, Ranjan Kumar ;
Das, Sudip Kumar .
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION, 2018, 116 :693-702
[6]   Removal of Cr(VI) from Its Aqueous Solution Using Green Adsorbent Pistachio Shell: a Fixed Bed Column Study and GA-ANN Modeling [J].
Banerjee M. ;
Bar N. ;
Basu R.K. ;
Das S.K. .
Water Conservation Science and Engineering, 2018, 3 (01) :19-31
[7]   Avocado seed powder: characterization and its application for crystal violet dye removal from aqueous solutions [J].
Bazzo, Alexandre ;
Adebayo, Matthew A. ;
Dias, Silvio L. P. ;
Lima, Eder C. ;
Vaghetti, Julio C. P. ;
de Oliveira, Eduardo R. ;
Leite, Anderson J. B. ;
Pavan, Flavio A. .
DESALINATION AND WATER TREATMENT, 2016, 57 (34) :15873-15888
[8]   Comparative study on removal of two basic dyes in aqueous medium by adsorption using activated carbon from Ziziphus lotus stones [J].
Boudechiche, Noreddine ;
Fares, Malika ;
Ouyahia, Siham ;
Yazid, Hynda ;
Trari, Mohamed ;
Sadaoui, Zahra .
MICROCHEMICAL JOURNAL, 2019, 146 :1010-1018
[9]   THE EXCHANGE ADSORPTION OF IONS FROM AQUEOUS SOLUTIONS BY ORGANIC ZEOLITES .2. [J].
BOYD, GE ;
ADAMSON, AW ;
MYERS, LS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1947, 69 (11) :2836-2848
[10]   Comparative study on adsorption of cationic and anionic dyes by smectite rich natural clays [J].
Chaari, Islem ;
Fakhfakh, Emna ;
Medhioub, Mounir ;
Jamoussi, Fakher .
JOURNAL OF MOLECULAR STRUCTURE, 2019, 1179 :672-677