3-Benzyl-7-bromo-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexahydro-1H-pyrrolo[3,4-b]quinoline

被引:0
作者
Chinnakali, K. [1 ]
Sudha, D. [1 ]
Jayagobi, M. [2 ]
Raghunathan, R. [2 ]
Fun, Hoong-Kun [3 ]
机构
[1] Anna Univ, Dept Phys, Madras 600025, Tamil Nadu, India
[2] Univ Madras, Dept Organ Chem, Madras 600025, Tamil Nadu, India
[3] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
DERIVATIVES;
D O I
10.1107/S1600536809045875
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C31H29BrN2O 2S, the pyrrolidine ring is in a twist conformation and the tetra-hydro-pyridine ring adopts an envelope conformation with the methine C atom adjacent to the NH group as the flap atom; the two rings are trans-fused. The bromo-benzene ring and the nearest phenyl ring form a dihedral angle of 82.72 (10)°. The benzyl phenyl and the tosyl phenyl rings are oriented at a dihedral angle of 75.57 (11)°. An intra-molecular N - H⋯π inter-action is observed. In the crystal, mol-ecules are linked into chains running along [101] by C - H⋯O hydrogen bonds and the chains are cross-linked via weak C - H⋯π inter-actions.
引用
收藏
页码:O3001 / U2066
页数:15
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