Synthesis and characterization of PS-block-PEO associative water-soluble polymers

被引：10
|
作者：
Boschet, F [1 ]
Branger, C [1 ]
Margaillan, A [1 ]
机构：
[1] Univ Toulon & Var, ISITV, Lab Chim Appl, MFS EA 1356,Equipe Accueil Mat Finalites Specif, F-83162 La Valette, France
来源：
EUROPEAN POLYMER JOURNAL | 2003年 / 39卷 / 02期
关键词：
fluorine; associative; PEO;
D O I：
10.1016/S0014-3057(02)00223-9
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We report the synthesis and structure determination of PS-block-PEO functionalized by fluorocarbon end-group (C8F17) via an ester bridge. The synthesis as done by an anionic polymerization of PS and POE terminated by grafting 3-perfluorooctylpropanoyle chloride (C8F17-CH4-COCl) onto PS-POE alcoholate. The structure has been characterized by a number of techniques: size exclusion chromatography. elementary analysis, UV spectroscopy, H-1 nuclear magnetic resonance. Those analyses have allowed the determination of the real molar mass of the copolymers and the percentage functionalization. Because of their well-defined structure. these copolymers can be used as model compounds for the determination of structure-property relationships. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：333 / 339
页数：7
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