The impact of polyol structure on the formation of Zn0.6Co0.4Fe2O4 spinel-based pigments

被引：55
作者：
Dippong, Thomas [1 ]
Levei, Erika Andrea [2 ]
Goga, Firuta [3 ]
Petean, Ioan [3 ]
Avram, Alexandra [3 ]
Cadar, Oana [2 ]
机构：
[1] Tech Univ Cluj Napoca, North Univ Ctr Baia Mare, Dept Chem & Biol, 76 Victoriei St, Baia Mare 430122, Romania
[2] Res Inst Analyt Instrumentat, INCDO INOE 2000, 67 Donath St, Cluj Napoca 400293, Romania
[3] Babes Bolyai Univ, Fac Chem & Chem Engn, 11 Arany Janos St, Cluj Napoca 400028, Romania
来源：
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY | 2019年 / 92卷 / 03期
关键词：
Ceramic pigments; Zn-Co ferrite spinel; Polyol; Glaze color; SOL-GEL SYNTHESIS; MAGNETIC-PROPERTIES; THERMAL-BEHAVIOR; NANOCOMPOSITES; NANOPARTICLES; COBALT;
D O I：
10.1007/s10971-019-05140-x
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The formation of Zn0.6Co0.4Fe2O4 spinel-based pigments by sol-gel method and post-annealing pathway and the impact of polyol structure on their properties were investigated. The phase evolution and mass changes of gels during annealing were assessed by thermal analysis. The differential thermal analysis revealed that above 400 degrees C the carboxylate precursors decompose to ZnFe2O4, CoFe2O4, and Zn2SiO4. X-ray diffraction pattern showed the presence of crystalline ZnFe2O4, CoFe2O4, Zn2SiO4, and SiO2, while Fourier transform infrared spectra confirmed the formation of metal-carboxylates and SiO2 matrix at 200 degrees C and formation of ZnFe2O4, CoFe2O4, and Zn2SiO4 at 1200 degrees C. The atomic force microscopy images showed spherical nanoparticles of size and shape varying with the polyol structure. The coloring properties and the potential ceramic applications of the obtained dark gray powders were tested by their embedding in opaque and transparent tile glazes and their application on ceramic tile.
引用
收藏
页码：736 / 744
页数：9
相关论文
共 23 条
  • [1] Effects of Solvent Diols on the Synthesis of ZnFe2O4 Particles and Their Use as Heterogeneous Photo-Fenton Catalysts
    Anchieta, Chayene Goncalves
    Cancelier, Adriano
    Mazutti, Marcio Antonio
    Jahn, Sergio Luiz
    Kuhn, Raquel Cristine
    Guendel, Andre
    Chiavone-Filho, Osvaldo
    Foletto, Edson Luiz
    [J]. MATERIALS, 2014, 7 (09): : 6281 - 6290
  • [2] [Anonymous], 1999, Joint Committee on Powder Diffraction Standards-International Center for Diffraction Data
  • [3] Antimicrobial activity of metal-substituted cobalt ferrite nanoparticles synthesized by sol-gel technique
    Ashour, A. H.
    El-Batal, Ahmed I.
    Maksoud, M. I. A. Abdel
    El-Sayyad, Gharieb S.
    Labib, Sh.
    Abdeltwab, E.
    El-Okr, M. M.
    [J]. PARTICUOLOGY, 2018, 40 : 141 - 151
  • [4] Analysis of structural and electrical properties of Ni2+:Zn2SiO4 ceramic powders by sol-gel method
    Babu, B. Chandra
    Buddhudu, S.
    [J]. JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2014, 70 (03) : 405 - 415
  • [5] Low temperature synthesis of zinc ferrite nanoparticles
    Bardhan, A.
    Ghosh, C. K.
    Mitra, M. K.
    Das, G. C.
    Mukherjee, S.
    Chattopadhyay, K. K.
    [J]. SOLID STATE SCIENCES, 2010, 12 (05) : 839 - 844
  • [6] Colour performance of ceramic nano-pigments
    Cavalcante, P. M.
    Dondi, M.
    Guarini, G.
    Raimondo, M.
    Baldi, G.
    [J]. DYES AND PIGMENTS, 2009, 80 (02) : 226 - 232
  • [7] Nano nickel ferrite (NiFe2O4) as anti-corrosion pigment for API 5L X-80 steel: An electrochemical study in acidic and saline media
    Chaudhry, Ali U.
    Mittal, Vikas
    Mishra, Brajendra
    [J]. DYES AND PIGMENTS, 2015, 118 : 18 - 26
  • [8] Influence of zinc substitution with cobalt on thermal behaviour, structure and morphology of zinc ferrite embedded in silica matrix
    Dippong, Thomas
    Goga, Firuta
    Levei, Erika-Andrea
    Cadar, Oana
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2019, 275 : 159 - 166
  • [9] Size and shape-controlled synthesis and characterization of CoFe2O4 nanoparticles embedded in a PVA-SiO2 hybrid matrix
    Dippong, Thomas
    Levei, Erika Andrea
    Cadar, Oana
    Goga, Firuta
    Barbu-Tudoran, Lucian
    Borodi, Gheorghe
    [J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2017, 128 : 121 - 130
  • [10] Sol-gel synthesis of CoFe2O4:SiO2 nanocomposites - insights into the thermal decomposition process of precursors
    Dippong, Thomas
    Levei, Erika Andrea
    Cadar, Oana
    Mesaros, Amalia
    Borodi, Gheorghe
    [J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2017, 125 : 169 - 177
123