catena-Poly[[tetrakis(μ-propionato-κ2O:O′) dicopper(II)]-μ-3-pyridyl-methanol-κ2N :O- [bis(3-propionato-κO)-bis(3-pyridylmethanol-κN)copper(II)]-μ-3-pyridylmethanol-κO:N]

被引：7
作者：
Moncol, Jan [1 ]
Maroszova, Jaroslava [1 ]
Melnik, Milan [1 ]
Koman, Marian [1 ]
机构：
[1] Slovak Univ Technol Bratislava, Dept Inorgan Chem, SK-81237 Bratislava, Slovakia
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2007年 / 63卷
关键词：
D O I：
10.1107/S0108270107004386
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [Cu-3(C3H5O2)(6)(C6H7NO)(4)](n), is composed of polymeric chains formed by alternating centro-symmetric Cu-2(mu-CH3CH2CO2)(4) and Cu(C3H5O2)(2)(C6H7NO) 2 units. These elemental units are linked by two bridging 3-pyridylmethanol (3PM) ligands. The Cu-2(mu-CH3CH2CO2)(4) group presents a centrosymmetric tetrabridged structure with four syn-syn bridging propionate ligands to which two 3PM molecules are bonded (through N), occupying the apical positions of each square-pyramidal polyhedron around the Cu-II ions. The remaining mononuclear group is centred around a third Cu-II ion, which lies on a symmetry centre and is bound to two monodentate propionate groups (through O), two monodentate 3PM molecules (through N) and two bridging 3PM molecules (through O), thus completing a square-bipyramidal CuO2N2O2 coordination.
引用
收藏
页码：M114 / M116
页数：3
相关论文
共 50 条
[21]   catena-Poly[nickel(II)-bis(μ-2-aminoethanesulfonato-κ3N,O:O′;κ3O:N,O′)] [J].
Yang, Feng ;
Wu, Zhi-Hong ;
Cai, Jin-Hua .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 :M748-U355
[22]   Poly[[[ bis[(2,2′-bipyridine-κ2N,N′)cadmium(II)]-bis[μ3-3-(4-carboxylatophenoxy)propionato-κ5O,O′:O′:O",O"′]] 4-hydroxybenzoic acid monohydrate] [J].
Kong, Li-Li ;
Gao, Shan ;
Huo, Li-Hua ;
Ng, Seik Weng .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 :M2938-U748
[23]   catena-Poly[[(di-2-pyridyl-N-amine)(propionato-O,O′)copper(II)]-μ-nitrato-O:O′] [J].
Youngme, S ;
Pakawatchai, C ;
Fun, HK .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1998, 54 :451-453
[24]   Bis(ferrocenecarboxylato-κO)bis(2-pyridylmethanol-κ2N,O)cobalt(II) [J].
Yu, Youzhu ;
Guo, Yuhua ;
Wang, Daqi ;
Li, Dacheng .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 :M753-U399
[25]   catena-Poly[[copper(II)-bis(μ-3-carboxypyridine-2-carboxylato)-κ3N,O2;O3;κ3O3:N,O2]methanol disolvate] [J].
Turner, David R. ;
Batten, Stuart R. .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 :M452-M454
[26]   catena-poly[[tetrakis(μ-3,5-dinitrobenzoato-O:O′)dicopper(II)]bis[(μ-3,5-dinitro-benzoato-O:O′)(methanol-O)copper(II)]] [J].
Hokelek, T ;
Mert, Y ;
Unaleroglu, C .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1998, 54 :310-313
[27]   catena-poly[[tetrakis(μ2-acetato-κ2O:O′)-dicopper(II)(Cu-Cu)]-μ2-acetato-κ2O:O′-[bis[μ2-3-(dimethylamino)-propan-1-olato]-κ2N,O:O;κ2O:N,O-bis-[(tetrahydrofuran-κO)copper(II)]]-μ2-acetato-κ2 O:O′] [J].
Shahid, Muhammad ;
Mazhar, Muhammad ;
Helliwell, Madeleine ;
Akhtar, Javeed ;
Ahmad, Kibriya .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M1139-U377
[28]   Chloro(di-2-pyridyl-κN-amine)(propionato- κ2O,O′)copper(II) monohydrate [J].
Youngme, S ;
Chinnakali, K ;
Chantrapromma, S ;
Fun, HK .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 :899-901
[29]   catena-poly[[tetrakis(μ-3,3-dimethylbutyrato-O:O′) dicopper(II)]-μ-3,3-dimethylbutyrato-O:O′-[bis (2,6-dimethylpyridine-N)copper(II)]-μ-3,3- dimethylbutyrato-O:O′] and tetrakis(μ-2,2-dimethylpropanoato-O:O′)bis- [(2,6-dimethylpyridine-N)copper(II)] [J].
Kani, Yoshiyuki ;
Tsuchimoto, Masanobu ;
Ohba, Shigeru ;
Matsushima, Hideaki ;
Tokii, Tadashi .
Acta Crystallographica, Section C: Crystal Structure Communications, 2000, 56 (08) :923-925
[30]   Bis(methyl 3-pyridyl-κN1-carbamate)bis(propionato-κO)copper(II)-water (4/1) [J].
Koman, M ;
Melník, M ;
Glowiak, T .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 :1604-1605
12345