Ultra-light and flexible pencil-trace anode for high performance potassium-ion and lithium-ion batteries

被引:70
作者
Tai, Zhixin [1 ]
Liu, Yajie [1 ]
Zhang, Qing [1 ]
Zhou, Tengfei [1 ]
Guo, Zaiping [1 ,2 ]
Liu, Hua Kun [1 ]
Dou, Shi Xue [1 ]
机构
[1] Univ Wollongong, Australian Inst Innovat Mat, Inst Superconducting & Elect Mat, Innovat Campus, North Wollongong, NSW 2500, Australia
[2] Univ Wollongong, Sch Mech Mat & Mechatron Engn, North Wollongong, NSW 2500, Australia
基金
澳大利亚研究理事会;
关键词
Current-collector-free; Flexible pencil-trace electrode; Potassium-ion battery; Lithium-ion battery; Layer-by-layer interconnected architecture;
D O I
10.1016/j.gee.2017.04.002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Engineering design of battery configurations and new battery system development are alternative approaches to achieve high performance batteries. A novel flexible and ultra-light graphite anode is fabricated by simple friction drawing on filter paper with a commercial 8B pencil. Compared with the traditional anode using copper foil as current collector, this innovative current-collector-free design presents capacity improvement of over 200% by reducing the inert weight of the electrode. The as-prepared pencil-trace electrode exhibits excellent rate performance in potassium-ion batteries (KIBs), significantly better than in lithium-ion batteries (LIBs), with capacity retention of 66% for the KIB vs. 28% for the LIB from 0.1 to 0.5 A g(-1). It also shows a high reversible capacity of similar to 230 mAh g(-1) at 0.2 A g(-1), 75% capacity retention over 350 cycles at 0.4 A g(-1) and the highest rate performance (based on the total electrode weight) among graphite electrodes for K+ storage reported so far. (C) 2017, Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd.
引用
收藏
页码:278 / 284
页数:7
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