Ultra-light and flexible pencil-trace anode for high performance potassium-ion and lithium-ion batteries

被引:70
作者
Tai, Zhixin [1 ]
Liu, Yajie [1 ]
Zhang, Qing [1 ]
Zhou, Tengfei [1 ]
Guo, Zaiping [1 ,2 ]
Liu, Hua Kun [1 ]
Dou, Shi Xue [1 ]
机构
[1] Univ Wollongong, Australian Inst Innovat Mat, Inst Superconducting & Elect Mat, Innovat Campus, North Wollongong, NSW 2500, Australia
[2] Univ Wollongong, Sch Mech Mat & Mechatron Engn, North Wollongong, NSW 2500, Australia
基金
澳大利亚研究理事会;
关键词
Current-collector-free; Flexible pencil-trace electrode; Potassium-ion battery; Lithium-ion battery; Layer-by-layer interconnected architecture;
D O I
10.1016/j.gee.2017.04.002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Engineering design of battery configurations and new battery system development are alternative approaches to achieve high performance batteries. A novel flexible and ultra-light graphite anode is fabricated by simple friction drawing on filter paper with a commercial 8B pencil. Compared with the traditional anode using copper foil as current collector, this innovative current-collector-free design presents capacity improvement of over 200% by reducing the inert weight of the electrode. The as-prepared pencil-trace electrode exhibits excellent rate performance in potassium-ion batteries (KIBs), significantly better than in lithium-ion batteries (LIBs), with capacity retention of 66% for the KIB vs. 28% for the LIB from 0.1 to 0.5 A g(-1). It also shows a high reversible capacity of similar to 230 mAh g(-1) at 0.2 A g(-1), 75% capacity retention over 350 cycles at 0.4 A g(-1) and the highest rate performance (based on the total electrode weight) among graphite electrodes for K+ storage reported so far. (C) 2017, Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd.
引用
收藏
页码:278 / 284
页数:7
相关论文
共 35 条
[1]   Ferromagnetism in lead graphite-pencils and magnetic composite with CoFe2O4 particles [J].
Bhowmik, R. N. .
COMPOSITES PART B-ENGINEERING, 2012, 43 (02) :503-509
[2]   Na+ intercalation pseudocapacitance in graphene-coupled titanium oxide enabling ultra-fast sodium storage and long-term cycling [J].
Chen, Chaoji ;
Wen, Yanwei ;
Hu, Xianluo ;
Ji, Xiulei ;
Yan, Mengyu ;
Mai, Liqiang ;
Hu, Pei ;
Shan, Bin ;
Huang, Yunhui .
NATURE COMMUNICATIONS, 2015, 6
[3]   Field electron emission from pencil-drawn cold cathodes [J].
Chen, Jiangtao ;
Yang, Bingjun ;
Liu, Xiahui ;
Yang, Juan ;
Yan, Xingbin .
APPLIED PHYSICS LETTERS, 2016, 108 (19)
[4]   Inkjet Printing of Single-Walled Carbon Nanotube/RuO2 Nanowire Supercapacitors on Cloth Fabrics and Flexible Substrates [J].
Chen, Pochiang ;
Chen, Haitian ;
Qiu, Jing ;
Zhou, Chongwu .
NANO RESEARCH, 2010, 3 (08) :594-603
[5]   Durable potassium ion battery electrodes from high-rate cointercalation into graphitic carbons [J].
Cohn, Adam P. ;
Muralidharan, Nitin ;
Carter, Rachel ;
Share, Keith ;
Oakes, Landon ;
Pint, Cary L. .
JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (39) :14954-14959
[6]   Continuous and Scalable Fabrication of Transparent Conducting Carbon Nanotube Films [J].
Dan, Budhadipta ;
Irvin, Glen C. ;
Pasquali, Matteo .
ACS NANO, 2009, 3 (04) :835-843
[7]   Electrical Energy Storage for the Grid: A Battery of Choices [J].
Dunn, Bruce ;
Kamath, Haresh ;
Tarascon, Jean-Marie .
SCIENCE, 2011, 334 (6058) :928-935
[8]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[9]   Flexible energy storage devices based on graphene paper [J].
Gwon, Hyeokjo ;
Kim, Hyun-Suk ;
Lee, Kye Ung ;
Seo, Dong-Hwa ;
Park, Yun Chang ;
Lee, Yun-Sung ;
Ahn, Byung Tae ;
Kang, Kisuk .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (04) :1277-1283
[10]   Printed energy storage devices by integration of electrodes and separators into single sheets of paper [J].
Hu, Liangbing ;
Wu, Hui ;
Cui, Yi .
APPLIED PHYSICS LETTERS, 2010, 96 (18)