Synthesis and characterization of some ruthenium mixed-ligand complexes

被引:1
作者
Shawakfeh, KQ [1 ]
Al-Rawashdeh, NAF [1 ]
Khader, S [1 ]
机构
[1] Jordan Univ Sci & Technol, Dept Appl Chem Sci, Irbid 22110, Jordan
关键词
D O I
10.1023/A:1021158931775
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The complexation reaction of trans-[RuCl2(Dpte)(2)] (Dpte - (diphenylthio)ethane) with mixed diimine ligands 2,2'-bipyridine, pyridylquinoline, 4,6-dichloro-2-(2-pyridyl)pyrimidine, 4,6-dichloro-5-methyl-2-(2-pyridyl)pyrimidine, and 4,6-dichloro-5-phenyl-2-(2-pyridyl)pyrimidine produces new Ru(II) mixed-ligand complexes. These complexes exhibit maximum photo- and chemical stability and high absorptivity. The above complexes have been characterized using IR, H-1 and C-13 NMR, electronic absorption spectroscopy, and elemental analysis.
引用
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页码:789 / 792
页数:4
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