Crystallization study of sol-gel derived 13-93 bioactive glass powder

被引：20

作者：

Nawaz, Qaisar ^{[1
]}

de Pablos-Martin, Araceli ^{[2
,5
]}

de Souza e Silva, Juliana Martins ^{[3
]}

Berthold, Lutz ^{[2
]}

Hurle, Katrin ^{[4
]}

Contreras Jaimes, Altair T. ^{[5
]}

Sitarz, Maciej ^{[6
]}

Brauer, Delia S. ^{[5
]}

Boccaccini, Aldo R. ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Inst Biomat, Dept Mat Sci & Engn, Cauerstr 6, D-91058 Erlangen, Germany

[2] Fraunhofer Inst Microstruct Mat & Syst IMWS, Walter Huelse Str 1, D-06120 Halle, Germany

[3] Martin Luther Univ Halle Wittenberg, Inst Phys MikroMD, Heinrich Damerow Str 4, D-06120 Halle, Germany

[4] Univ Erlangen Nurnberg, Mineral, GeoZentrum Nordbayern, Schlossgarten 5a, D-91054 Erlangen, Germany

[5] Friedrich Schiller Univ, Otto Schott Inst Mat Res, Fraunhoferstr 6, D-07743 Jena, Germany

[6] AGH Univ Sci & Technol, Fac Mat Sci & Ceram, Al Mickiewicza 30, PL-30059 Krakow, Poland

来源：

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 2021年 / 41卷 / 02期

关键词：

Bioactive glasses; Sol-gel; Sintering of 13-93 bioactive glass; Crystallization behavior; Rietveld refinement; IN-VITRO PERFORMANCE; CRYSTAL-STRUCTURE; 45S5; SCAFFOLDS; MICROSTRUCTURE; IDENTIFICATION; TEMPERATURE; CERAMICS; ZIRCONIA; BEHAVIOR;

D O I：

10.1016/j.jeurceramsoc.2020.09.052

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Multicomponent silicate bioactive glass (BG) (53SiO(2)-20CaO-6Na(2)O-4P(2)O(5)-12K(2)O(5)MgO in wt. %) (13-93 composition) was prepared via the sol-gel process. The influence of thermal treatment on the crystallization was evaluated using differential scanning calorimetry (DSC), X-ray diffraction (XRD), transmission electron microscopy (TEM) and X-ray nano-computed tomography (nano-CT). The temperature and time of the thermal treatment strongly influenced the formation of the crystalline phases. The preliminary outcomes demonstrate the possibility of tailoring the crystallinity of 13-93 BG powder in the range 5-43 wt. % by controlling the temperature and time of the heat treatment. The microstructure of powders sintered at two different temperatures (650 degrees C and 700 degrees C from 30 min to 4 h) was evaluated by TEM. X-ray nano-computed tomography (nano-CT) was used to visualize the 3D morphology and distribution of crystallization areas in the samples in powder form. A large range between the glass transformation and the crystallization temperatures is observed, which provides the prospect of a suitable material to manufacture directly 3D structures (e.g. porous scaffolds) without an intermediate processing step.

引用

页码：1695 / 1706

页数：12

共 64 条

[1]

Arstila H, 2005, GLASS TECHNOL, V46, P138

[2]

Arstila H., 2004, T TECH PUBL, P67

[3] Liquidus temperatures of bioactive glasses [J].

Arstila, Hanna ;

Tukiainen, Mikko ;

Taipale, Susanne ;

Kellomaki, Minna ;

Hupa, Leena .

GLASS - THE CHALLENGE FOR THE 21ST CENTURY, 2008, 39-40 :287-+

[4] CRYSTAL-STRUCTURE OF CADMIUM CESIUM TRIMETAPHOSPHATE (CDCSP309) [J].

AVERBUCHPOUCHOT, MT ;

DURIF, A .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (OCT) :3114-3116

[5] Synthesis and characterisation of sol gel derived bioactive glass for biomedical applications [J].

Balamurugan, A. ;

Sockalingum, G. ;

Michel, J. ;

Faure, J. ;

Banchet, V. ;

Wortham, L. ;

Bouthors, S. ;

Laurent-Maquin, D. ;

Balossier, G. .

MATERIALS LETTERS, 2006, 60 (29-30) :3752-3757

[6] Crystallization Kinetics and Structural Properties of the 45S5 Bioactive Glass and Glass-Ceramic Fiber Doped with Eu3+ [J].

Baranowska, Agata ;

Lesniak, Magdalena ;

Kochanowicz, Marcin ;

Zmojda, Jacek ;

Miluski, Piotr ;

Dorosz, Dominik .

MATERIALS, 2020, 13 (06)

[7] Evaluation of bone regeneration, angiogenesis, and hydroxyapatite conversion in critical-sized rat calvarial defects implanted with bioactive glass scaffolds [J].

Bi, Lianxiang ;

Jung, Steve ;

Day, Delbert ;

Neidig, Katie ;

Dusevich, Vladimir ;

Eick, David ;

Bonewald, Lynda .

JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A, 2012, 100A (12) :3267-3275

[8] Sintering and concomitant crystallization of bioactive glasses [J].

Blaess, Carsten ;

Mueller, Ralf ;

Poologasundarampillai, Gowsihan ;

Brauer, Delia S. .

INTERNATIONAL JOURNAL OF APPLIED GLASS SCIENCE, 2019, 10 (04) :449-462

[9] Natural Medicine Compounds in Bone Tissue Engineering [J].

Bose, Susmita ;

Sarkar, Naboneeta .

TRENDS IN BIOTECHNOLOGY, 2020, 38 (04) :404-417

[10]

Brauer DS, 2012, PHYS CHEM GLASSES-B, V53, P27

← 1 2 3 4 5 6 7 →