155Gd Mossbauer spectroscopic study of GdM (CN)6•4H2O (M = CrIII, FeIII and CoIII) and KGdM (CN)6•3H2O (M = FeII and RuII)

被引：0

作者：

Wang, JH ^{[1
]}

Abe, J ^{[1
]}

Kitazawa, T ^{[1
]}

Takahashi, M ^{[1
]}

Takeda, M ^{[1
]}

机构：

[1] Toho Univ, Fac Sci, Dept Chem, Funabashi, Chiba 2748510, Japan

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES | 2002年 / 57卷 / 6-7期

关键词：

Gd-155 Mossbauer spectroscopy; quadrupole coupling constant; Gd(III) cyano polymeric complex; orthorhombic distortion;

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Gd-155 Mossbauer spectroscopic studies of the title complexes have been performed. Although the Gd-155 isomer shifts (delta) varied scarcely, the quadrupole coupling constants (e(2)qQ) changed in the range 4.07-4.81 mm s(-1). The e(2)qQ values of KGdM(CN)(6) . 3H(2)O (M = Fe-II and Ru-II) are larger than those of GdM(CN)(6) . 4H(2)O (M = Cr-III, Fe-III, and Co-III), these values increasing with increasing orthorhombic distortion of the crystal structures. A relationship between the e(2)qQ values and the ionic radii of the transition metal ions has also been recognized.

引用

页码：581 / 585

页数：5