Adsorption of environmental pollutants using magnetic hybrid nanoparticles modified with β-cyclodextrin

被引:70
|
作者
Wang, Niejun [1 ,2 ]
Zhou, Lilin [1 ]
Guo, Jun [1 ]
Ye, Qiquan [1 ]
Lin, Jin-Ming [2 ]
Yuan, Jinying [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China
[2] Tsinghua Univ, Dept Chem, Beijing Key Lab Microanalyt Method & Instrumentat, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
Magnetic nanoparticles; Radical polymerization; beta-Cyclodextrin; Adsorption; Environmental pollutants; BISPHENOL-A; DRUG CARRIER; SHELL; WATER; FUNCTIONALIZATION; CHROMATOGRAPHY; NANOCRYSTALS; SEPARATION; COMPLEXES; CATALYST;
D O I
10.1016/j.apsusc.2014.03.054
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Graft through strategy was utilized to coat magnetic Fe3O4 nanoparticles with poly(glycidyl methacrylate) using ordinary radical polymerization and then p-cyclodextrin was linked onto the surface of nanoparticles. With these nanoparticles modified with cyclodextrin groups, adsorption of two model environmental pollutants, bisphenol A and copper ions, was studied. Host-guest interactions between cyclodextrin and aromatic molecules had a great contribution to the adsorption of bisphenol A, while multiple hydroxyls of cyclodextrin also helped the adsorption of copper ions. These magnetic nanopartides could be applied in the elimination, enrichment and detection of some environmental pollutants. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:267 / 273
页数:7
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