Morpholine-β-iodophenylacetylene (1/1) revisited:: an exceptionally short I•••N contact

被引：11

作者：

Batsanov, AS ^{[1
]}

Howard, JAK ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2000年 / 56卷

关键词：

D O I：

10.1107/S0108270199014705

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex, C8H5I . C4H9NO, has an intermolecular charge-transfer bond N ... I of 2.712(2) Angstrom, shorter than supposed earlier and the shortest known so far. Morpholine molecules related by a b translation are linked to form a chain by N-H ... O hydrogen bonds [N ... O 3.110 (3) Angstrom].

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页码：252 / 253

页数：2

相关论文

共 13 条

[1]

BATSANOV SS, 1990, SOV SCI REV B, V15, P1

[2]

BAUGHMAN RH, 1994, J ORG CHEM, V29, P964

[3] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[4] MUTUAL ARRANGEMENT OF IODO-CYANO-ACETYLENE MOLECULES IN SOLID [J].

BORGEN, B ;

HASSEL, O ;

ROMMING, C .

ACTA CHEMICA SCANDINAVICA, 1962, 16 (10) :2469-&

[5] GENERAL DEFINITION OF RING PUCKERING COORDINATES [J].

CREMER, D ;

POPLE, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1354-1358

[6] SOLID ADDUCTS OF HEXAMETHYLENETETRAMINE AND TRIHALOGENOMETHANES - CRYSTAL STRUCTURE OF 1-1 IODOFORM COMPOUND [J].

DAHL, T ;

HASSEL, O .

ACTA CHEMICA SCANDINAVICA, 1970, 24 (02) :377-&

[7] NOVEL MOLECULAR CONDUCTORS, (DIETS)(4)M(CN)(4) (M=NI, PT) - HIGHLY RETICULATED DONOR-CENTER-DOT-CENTER-DOT-CENTER-DOT-ANION CONTACTS BY -I-CENTER-DOT-CENTER-DOT-CENTER-DOT-NC- INTERACTION [J].

IMAKUBO, T ;

SAWA, H ;

KATO, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) :1667-1668

[8] A REVISION OF VANDERWAALS ATOMIC RADII FOR MOLECULAR-CRYSTALS - N, O, F, S, CL, SE, BR AND I BONDED TO CARBON [J].

NYBURG, SC ;

FAERMAN, CH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :274-279

[9] Intermolecular nonbonded contact distances in organic crystal structures: Comparison with distances expected from van der Waals radii [J].

Rowland, RS ;

Taylor, R .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (18) :7384-7391

[10]

SHELDRICK GM, 1995, SHELXTL VERSION 5 04