Recent progress in catalytic conversions of carbon dioxide

被引:489
作者
Maeda, Chihiro [1 ]
Miyazaki, Yuki [1 ]
Ema, Tadashi [1 ]
机构
[1] Okayama Univ, Grad Sch Nat Sci & Technol, Div Chem & Biotechnol, Tsushima, Okayama 7008530, Japan
关键词
N-HETEROCYCLIC CARBENES; CYCLIC CARBONATES; DIRECT CARBOXYLATION; ALTERNATING COPOLYMERIZATION; BIFUNCTIONAL CATALYST; EFFICIENT CATALYST; CHEMICAL FIXATION; METAL-COMPLEXES; IONIC LIQUIDS; CO2;
D O I
10.1039/c3cy00993a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Chemical fixation of carbon dioxide (CO2), which is an inexpensive and renewable carbon source, is becoming more and more important. The development of both new reactions and new catalysts is needed to overcome the kinetic and thermodynamic stability of CO2. Organic and metal catalysts with unique and excellent activity and selectivity have been developed for various chemical conversions of CO2. In this perspective, we provide an overview of the recent progress in this field, classifying it into several categories, where each research is concisely summarized one by one using a single reaction scheme, a representative catalyst structure, and/or a catalytic cycle.
引用
收藏
页码:1482 / 1497
页数:16
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