Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal-Organic Framework Thin Film

被引：124

作者：

Lu, Chunjing ^{[1
]}

Ben, Teng ^{[2
]}

Xu, Shixian ^{[1
]}

Qiu, Shilun ^{[1
]}

机构：

[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China

[2] Jilin Univ, Dept Chem, Changchun 130012, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 25期

基金：

中国国家自然科学基金;

关键词：

adsorption; conducting polymers; electrochemical synthesis; metal-organic frameworks; polyaniline; ELECTRICAL-CONDUCTIVITY; RADICAL POLYMERIZATION; POLYANILINE NANOWIRES; CRYSTAL; ADSORPTION; MEMBRANE; IODINE; ELECTROPOLYMERIZATION; POLYPYRROLE; NANOTUBES;

D O I：

10.1002/anie.201402950

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new approach to preparing 3D microporous conductive polymer has been demonstrated in the electrochemical synthesis of a porous polyaniline network with the utilization of a MOF thin film supported on a conducting substrate. The prepared porous polyaniline with well-defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m(2) g(-1) and a high electric conductivity of 0.125 S cm(-1) when doped with I-2, which is superior to existing porous conducting materials of porous MOFs, CMPs, and COFs.

引用

页码：6454 / 6458

页数：5

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