Synthesis, structure and luminescent property of a new europium-based coordination polymer constructed from biphenyl-3,4′,5-tricarboxylic acid

被引：6
作者：
Yan, Dan [1 ]
Duan, Qian [1 ]
机构：
[1] Changchun Univ Sci & Technol, Sch Mat Sci & Engn, Changchun 130022, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 36卷
关键词：
Metal-organic framework; Biphenyl-3,4 ',5-tricarboxylic acid(H3BPT); Europium; Structural analysis; Luminescence; METAL-ORGANIC FRAMEWORKS; PHOTOLUMINESCENCE;
D O I：
10.1016/j.inoche.2013.09.005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 3D lanthanide metal-organic framework Eu(BPT)(DMF)(H2O)center dot(H2O)(0.5)] (1) has been synthesized by self-assembly of Eu(III) ions and ligand biphenyl-3, 4', 5-tricarboxylate under solvothermal reaction conditions. X-ray crystallography reveals that 1 exhibits a (3, 6)-connected topology, with dinuclear europium clusters as 6-connected nodes and C-2-symmetric ligands BPT as 3-connected nodes. In addition, the luminescence sensitization of 1 via excitation of the ligand is highly efficient. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：188 / 191
页数：4
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