Synthesis, structure and luminescent property of a new europium-based coordination polymer constructed from biphenyl-3,4′,5-tricarboxylic acid

被引：6
作者：
Yan, Dan [1 ]
Duan, Qian [1 ]
机构：
[1] Changchun Univ Sci & Technol, Sch Mat Sci & Engn, Changchun 130022, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 36卷
关键词：
Metal-organic framework; Biphenyl-3,4 ',5-tricarboxylic acid(H3BPT); Europium; Structural analysis; Luminescence; METAL-ORGANIC FRAMEWORKS; PHOTOLUMINESCENCE;
D O I：
10.1016/j.inoche.2013.09.005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 3D lanthanide metal-organic framework Eu(BPT)(DMF)(H2O)center dot(H2O)(0.5)] (1) has been synthesized by self-assembly of Eu(III) ions and ligand biphenyl-3, 4', 5-tricarboxylate under solvothermal reaction conditions. X-ray crystallography reveals that 1 exhibits a (3, 6)-connected topology, with dinuclear europium clusters as 6-connected nodes and C-2-symmetric ligands BPT as 3-connected nodes. In addition, the luminescence sensitization of 1 via excitation of the ligand is highly efficient. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：188 / 191
页数：4
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共 31 条
  • [1] Luminescent Functional Metal-Organic Frameworks
    Cui, Yuanjing
    Yue, Yanfeng
    Qian, Guodong
    Chen, Banglin
    [J]. CHEMICAL REVIEWS, 2012, 112 (02) : 1126 - 1162
  • [2] A lanthanide metal-organic framework with high thermal stability and available Lewis-acid metal sites
    Guo, Xiaodan
    Zhu, Guangshan
    Li, Zhongyue
    Sun, Fuxing
    Yang, Zhenghong
    Qiu, Shilun
    [J]. CHEMICAL COMMUNICATIONS, 2006, (30) : 3172 - 3174
  • [3] A robust near infrared luminescent ytterbium metal-organic framework for sensing of small molecules
    Guo, Zhiyong
    Xu, Hui
    Su, Shengqun
    Cai, Jianfeng
    Dang, Song
    Xiang, Shengchang
    Qian, Guodong
    Zhang, Hongjie
    O'Keeffe, Michael
    Chen, Banglin
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (19) : 5551 - 5553
  • [4] Flexible metal-organic supramolecular isomers for gas separation
    Kishan, Motkuri Radha
    Tian, Jian
    Thallapally, Praveen K.
    Fernandez, Carlos A.
    Dalgarno, Scott J.
    Warren, John E.
    McGrail, B. Peter
    Atwood, Jerry L.
    [J]. CHEMICAL COMMUNICATIONS, 2010, 46 (04) : 538 - 540
  • [5] Route to a Family of Robust, Non-interpenetrated Metal-Organic Frameworks with pto-like Topology
    Klein, Nicole
    Senkovska, Irena
    Baburin, Igor A.
    Gruenker, Ronny
    Stoeck, Ulrich
    Schlichtenmayer, Maurice
    Streppel, Barbara
    Mueller, Uwe
    Leoni, Stefano
    Hirscher, Michael
    Kaskel, Stefan
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (46) : 13007 - 13016
  • [6] A systematic study of the photophysical processes in polydentate triphenylene-functionalized Eu3+, Tb3+, Nd3+, Yb3+, and Er3+ complexes
    Klink, SI
    Grave, L
    Reinhoudt, DN
    van Veggel, FCJM
    Werts, MHV
    Geurts, FAJ
    Hofstraat, JW
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (23) : 5457 - 5468
  • [7] Synthesis, Structure, and Magnetic Properties of Cobalt(II) Coordination Polymers from a New Tripodal Carboxylate Ligand: Weak Ferromagnetisin and Metamagnetism
    Lama, Prem
    Aijaz, Arshad
    Sanudo, E. Carolina
    Bharadwaj, Parimal K.
    [J]. CRYSTAL GROWTH & DESIGN, 2010, 10 (01) : 283 - 290
  • [8] Microporous Lanthanide-Organic Frameworks with Open Metal Sites: Unexpected Sorption Propensity and Multifunctional Properties
    Lee, Woo Ram
    Ryu, Dae Won
    Lee, Jin Wuk
    Yoon, Jung Hee
    Koh, Eui Kwan
    Hong, Chang Seop
    [J]. INORGANIC CHEMISTRY, 2010, 49 (11) : 4723 - 4725
  • [9] Metal-Organic Frameworks for Separations
    Li, Jian-Rong
    Sculley, Julian
    Zhou, Hong-Cai
    [J]. CHEMICAL REVIEWS, 2012, 112 (02) : 869 - 932
  • [10] Solvent-Dependent Formation of Cd(II) Coordination Polymers Based on a C2-Symmetric Tricarboxylate Linker
    Li, Lina
    Wang, Shuyun
    Chen, Tianliang
    Sun, Zhihua
    Luo, Junhua
    Hong, Maochun
    [J]. CRYSTAL GROWTH & DESIGN, 2012, 12 (08) : 4109 - 4115
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