The first P-N containing RuCl3NO complex:: fac-[RuCl3(NO)(P-N)] (P-N = [o-(N,N-dimethylamino)phenyl]diphenylphosphine)

被引：18
作者：
Cavarzan, Deividi A.
Caetano, Fabio R.
Romualdo, Lincoln L.
do Nascimento, Fabio B.
Batista, Alzir A.
Ellena, Javier
Barison, Andersson
de Araujo, Marcio P.
机构：
[1] Univ Fed Parana, Dept Quim, Ctr Politecn, BR-81531990 Curitiba, Parana, Brazil
[2] Univ Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP, Brazil
[3] Univ Sao Paulo, Inst Fis Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 12期
关键词：
nitrosyl ruthenium; P-N ligand; X-ray structure;
D O I：
10.1016/j.inoche.2006.08.001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Complex fac-[RuCl3(NO)(P-N)] was synthesized from [RuCl3(H2O)(2)(NO)] in methanol solution under reflux. The orange solid obtained was characterized by NMR ((31)p{H-1}, H-1, C-13) and, cyclic voltammetry, ESI-MS, IR, elemental analysis and X-ray diffraction structure determination. The (31)p{H-1} reveals the presence of singlet at 36 ppm. IR N-O stretching as KBr pellets or CH2Cl2 solution presented 1866 cm(-1) and 1872 cm(-1), respectively. (C) 2006 Elsevier B.V. All rights reserved.
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收藏
页码：1247 / 1250
页数：4
相关论文
共 32 条
[1]   Ruthenium(III) polyaminocarboxylate complexes: Efficient and effective nitric oxide scavengers [J].
Cameron, BR ;
Darkes, MC ;
Yee, H ;
Olsen, M ;
Fricker, SP ;
Skerlj, RT ;
Bridger, GJ ;
Davies, NA ;
Wilson, MT ;
Rose, DJ ;
Zubieta, J .
INORGANIC CHEMISTRY, 2003, 42 (06) :1868-1876
[2]   Ruthenium(III) triazacyclononane dithiocarbamate, pyridinecarboxylate, or aminocarboxylate complexes as scavengers of nitric oxide [J].
Cameron, BR ;
Darkes, MC ;
Baird, IR ;
Skerlj, RT ;
Santucci, ZL ;
Fricker, SP .
INORGANIC CHEMISTRY, 2003, 42 (13) :4102-4108
[3]   Chiral phosphinooxazoline-ruthenium(II) and -osmium(II) complexes as catalysts in Diels-Alder reactions [J].
Carmona, D ;
Vega, C ;
García, N ;
Lahoz, FJ ;
Elipe, S ;
Oro, LA ;
Lamata, MP ;
Viguri, F ;
Borao, R .
ORGANOMETALLICS, 2006, 25 (07) :1592-1606
[4]   CALCULATION OF ABSORPTION CORRECTIONS FOR CAMERA AND DIFFRACTOMETER DATA [J].
COPPENS, P ;
LEISEROWITZ, L ;
RABINOVICH, D .
ACTA CRYSTALLOGRAPHICA, 1965, 18 :1035-+
[5]   Coordination and redox chemistry of substituted-polypyridyl complexes of ruthenium [J].
Dovletoglou, A ;
Adeyemi, SA ;
Meyer, TJ .
INORGANIC CHEMISTRY, 1996, 35 (14) :4120-4127
[6]   Luminescent ruthenium(II)- and rhenium(I)-diimine wires bind nitric oxide synthase [J].
Dunn, AR ;
Belliston-Bittner, W ;
Winkler, JR ;
Getzoff, ED ;
Stuehr, DJ ;
Gray, HB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (14) :5169-5173
[7]  
Enraf-Nonius, 1997, COLLECT
[8]   Reaction mechanisms relevant to the formation of iron and ruthenium nitric oxide complexes [J].
Ford, PC ;
Laverman, LE .
COORDINATION CHEMISTRY REVIEWS, 2005, 249 (3-4) :391-403
[9]   Reactivity of trans-[Ru(NH3)4P(OEt)3NO]X3 (X = PF6-, CF3COO-):: modulation of the release of NO by the trans-effect [J].
Lopes, LGF ;
Castellano, EE ;
Ferreira, AG ;
Davanzo, CU ;
Clarke, MJ ;
Franco, DW .
INORGANICA CHIMICA ACTA, 2005, 358 (10) :2883-2890
[10]  
MA EFS, 1999, THESIS U BRIT COLUMB
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