Intercalation and bilayer formation of phospholipids in layered synthetic mica .2. solvent effect of the intercalation reaction of natural and reduced-type phosphatidylcholines

被引：12
作者：
Kanzaki, Y
Hayashi, M
Minami, C
Inoue, Y
Kogure, M
Watanabe, Y
Tanaka, T
机构：
[1] Showa Coll. of Pharmaceutical Sci., Machida, Tokyo 194, 3-3165, Higashi-Tamagawagakuen
来源：
LANGMUIR | 1997年 / 13卷 / 14期
关键词：
D O I：
10.1021/la9608371
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The intercalation reaction of natural phospholipids into synthetic mica was examined by means of chemical analysis and X-ray diffraction analysis. The rate of the intercalation was fast from a chloroform solution of lipids, and bilayer formation in the solid phase was perfect. On the other hand, the rate of intercalation was rather slow in ethanol solution, and bilayer formation was not always successful. Such a solvent effect was accountable due to the solvation of the hydrophilic quaternary ammonium head either in the solution phase or in the solid phase.
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收藏
页码：3674 / 3680
页数：7
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