Nitroxide-mediated miniemulsion polymerization of n-butyl acrylate:: Synthesis of controlled homopolymers and gradient copolymers with styrene

被引：0
|
作者：
Farcet, C [1 ]
Charleux, B [1 ]
机构：
[1] Univ Paris 06, CNRS, UMR 7610, Lab Chim Macromol, F-75252 Paris, France
来源：
MACROMOLECULAR SYMPOSIA | 2002年 / 182卷
关键词：
D O I：
10.1002/1521-3900(200206)182:1<249::AID-MASY249>3.0.CO;2-9
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Controlled free-radical homopolymerization of n-butyl acrylate and its copolymerization with styrene have been studied in aqueous miniemulsion, using an acyclic beta-phosphonylated nitroxide as a mediator, the N-tert-butyl-N-(1-diethylphosphono-2,2-dimethylpropyl) nitroxide, also called SG1. Polymerization kinetics have been studied and characterization of the (co)polymers has been performed, demonstrating the successful synthesis of well-defined poly(n-butyl acrylate) homopolymers and poly(n-butyl acrylate-co-styrene) gradient copolymers.
引用
收藏
页码：249 / 260
页数：12
相关论文
共 50 条
  • [1] Triblock copolymers based on styrene and n-butyl acrylate by nitroxide-mediated radical polymerization:: Problems and solutions
    Robin, S
    Gnanou, Y
    MACROMOLECULAR SYMPOSIA, 2001, 165 : 43 - 53
  • [2] Poly(n-butyl acrylate) homopolymer and poly[n-butyl acrylate-b-(n-butyl acrylate-co-styrene)] block copolymer prepared via nitroxide-mediated living/controlled radical polymerization in miniemulsion
    Farcet, C
    Charleux, B
    Pirri, R
    MACROMOLECULES, 2001, 34 (12) : 3823 - 3826
  • [3] Nitroxide-mediated miniemulsion acrylate polymerization
    Keoshkerian, B
    Szkurhan, AR
    Georges, MK
    MACROMOLECULES, 2001, 34 (19) : 6531 - 6532
  • [4] Nitroxide-Mediated Polymerization of n-Butyl Acrylate and D-Limonene
    Ren, Shanshan
    Dube, Marc A.
    MACROMOLECULAR SYMPOSIA, 2016, 360 (01) : 152 - 159
  • [5] Nitroxide-mediated styrene miniemulsion polymerization
    Cunningham, MF
    Xie, M
    McAuley, KB
    Keoshkerian, B
    Georges, MK
    MACROMOLECULES, 2002, 35 (01) : 59 - 66
  • [6] Nitroxide-Mediated Radical Polymerization in Microemulsion (Microemulsion NMP) of n-Butyl Acrylate
    Tomoeda, Seita
    Kitayama, Yukiya
    Wakamatsu, Junpei
    Minami, Hideto
    Zetterlund, Per B.
    Okubo, Masayoshi
    MACROMOLECULES, 2011, 44 (14) : 5599 - 5604
  • [7] Novel SG1-Based water-soluble alkoxyamine for nitroxide-mediated controlled free-radical polymerization of styrene and n-butyl acrylate in miniemulsion
    Nicolas, J
    Charleux, B
    Guerret, O
    Magnet, S
    MACROMOLECULES, 2004, 37 (12) : 4453 - 4463
  • [8] Synthesis of polystyrene-block-poly (butyl acrylate) copolymers using nitroxide-mediated living radical polymerization in miniemulsion
    Tortosa, K
    Smith, JA
    Cunningham, MF
    MACROMOLECULAR RAPID COMMUNICATIONS, 2001, 22 (12) : 957 - 961
  • [9] n-butyl acrylate polymerization mediated by a PROXYL nitroxide
    Cameron, NR
    Reid, AJ
    MACROMOLECULES, 2002, 35 (27) : 9890 - 9895
  • [10] Nitroxide-mediated controlled free-radical emulsion polymerization of styrene and n-butyl acrylate with a water-soluble alkoxyamine as initiator
    Nicolas, J
    Charleux, B
    Guerret, O
    Magnet, SP
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (45) : 6186 - 6189
12345